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On the dynamics of excitations in disordered systems
Authors:Shaul Mukamel
Institution:(1) Department of Chemistry, University of Rochester, 14627 Rochester, New York
Abstract:A new, time-local (TL) reduced equation of motion for the probability distribution of excitations in a disordered system is developed. ToO(k2) the TL equation results in a Gaussian spatial probability distribution, i.e, langP(r, t)rang = (2pgrxgr)1/2]–dexp(-r2/2xgr2), where xgr = xgr(t) is a correlation length, andr = ¦r¦. The corresponding distribution derived from the Hahn-Zwanzig (HZ) equation is more complicated and assumes the asymptotic (rrarr infin) form: langP(r, s)rang(sxgr d )–1exp(–r/xgr) · (r/xgr)(1-d)/2 where xgr = xgr(s),d is the space dimensionality, ands is the Laplace transform variable conjugate tot. The HZ distribution generalizes the scaling form suggested by Alexanderet al. ford= 1. In the Markov limit xgr(t)radict, xgr(s)1/radics, and the two distributions are identical (ordinary diffusion).
Keywords:Disordered system  diffusion  master equations  non-Markovian dynamics
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