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The derivation of the quantum kinetic equation and the two-time resolvent method
Authors:T Y Petrosky  W C Schieve
Institution:(1) Center for Studies in Statistical Mechanics, University of Texas, 78712 Austin, Texas
Abstract:Van Hove's partial density matrix,rgr E (t), in his generalized master equation is interpreted as a Wigner representation of ldquotwo-time dyadrdquo for ldquoenergy Erdquo and ldquotime trdquo. This interpretation enables us to integrate the ldquoenergyrdquoE in Van Hove's master equation. The resultant equation is of non-Markov type on two time parameters. Starting with this master equation, the derivation of quantum kinetic equations, including the second-order approximation in the density expansion, is discussed. The scaling of the quantum kinetic equation is examined in detail for a system in which particles interact through the delta shell potential. It is shown that the quantum kinetic equation, including three-particle scattering, may exist for the physical situations of low-energy scattering,high-energy scattering, and for resonance scattering for time scales of the system sufficiently separated. In deriving the quantum kinetic equation, a factorization theorem form-particle distribution functions is proved to arbitrary order in perturbation expansion.
Keywords:Van Hove's two-time method  Wigner function on energy and time  two-time dyad  Liouvillian  energy superoperator  quantum kinetic equation  factorization theorem  second-order approximation in density expansion  three-particle scattering  delta shell potential" target="_blank">gif" alt="delta" align="BASELINE" BORDER="0"> shell potential  resonance scattering
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