Quantum theory of dissipative processes: The Markov approximation revisited

Adopting the standard mathematical framework for describing reduced dynamics, we derive two formal identities for the density operator of an open quantum system. Each of these is equivalent to the old Nakajima-Zwanzig equation. The first identity is local in time. It contains the inverse of the dynamical map which govern the evolution of the density operator. We indicate a time interval on which this inverse exists. The second identity constitutes a suitable starting point for going beyond the Markov approximation in a controlled way. On the basis of the Bloch equations we argue once more that in studying quantum dissipation one has to pay attention to the von Neumann conditions. In the Nakajima-Zwanzig equation we make the first Born approximation. The ensuing master equation possesses the correct weak-coupling limit. While proving this rather obvious but at the same time important statement, we elucidate the mathematical methods which underlie the weak-coupling limit. Moving to a two-dimensional Hilbert space, we find that both for short and for long times our approximate master equation respects the von Neumann conditions. Assuming exponential decay for correlation functions, we propose a physical limit in which the solutions for the density operator become Markovian in character. We confirm the well-known statement that, as seen from a macroscopic standpoint, the system starts from an effective initial condition. The approach to equilibrium is exponential. The accessory relaxation constants can differ from the usual Bloch parameters and by more than 50%.