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Reprint of : Thermoelectricity without absorbing energy from the heat sources
Institution:1. Laboratoire de Physique et Modélisation des Milieux Condensés (UMR 5493), Université Grenoble Alpes and CNRS, Maison des Magistères, BP 166, 38042 Grenoble, France;2. Instituto de Ciencia de Materiales de Madrid, CSIC, Cantoblanco, 28049 Madrid, Spain;3. JARA Institute for Quantum Information, RWTH Aachen University, D-52056 Aachen, Germany;4. Department of Microtechnology and Nanoscience (MC2), Chalmers University of Technology, SE-41298 Göteborg, Sweden;1. Université de Nice Sophia-Antipolis, INLN, CNRS, 06560 Valbonne, France;2. Institut-Lorentz, Universiteit Leiden, P.O. Box 9506, 2300 RA Leiden, The Netherlands;3. Aix Marseille Université, CNRS, CPT, UMR 7332, 13288 Marseille, France;4. Université de Toulon, CNRS, CPT, UMR 7332, 83957 La Garde, France;1. Univ. Grenoble Alpes, INAC-SPSMS, F-38000 Grenoble, France;2. CEA, INAC-SPSMS, F-38000 Grenoble, France;3. Department of Physics, College of William and Mary, Williamsburg, Virginia 23187, USA;4. Kavli Institute of NanoScience, Delft University of Technology, Lorentzweg 1, NL-2628 CJ, Delft, The Netherlands;1. Institute of Molecular Physics, Polish Academy of Sciences, ul. M. Smoluchowskiego 17, 60-179 Poznań, Poland;2. Jo?ef Stefan Institute, Ljubljana, Slovenia;3. Faculty of Mathematics and Physics, University of Ljubljana, Ljubljana, Slovenia;1. Institut de Physique et de Chimie des Matériaux de Strasbourg, Université de Strasbourg, CNRS UMR 7504, 23 rue du Loess, BP 43, F-67034 Strasbourg Cedex 2, France;2. Freiburg Institute for Advanced Studies, Albert-Ludwigs-Universität, Albertstr. 19, D-79104 Freiburg, Germany
Abstract:We analyze the power output of a quantum dot machine coupled to two electronic reservoirs via thermoelectric contacts, and to two thermal reservoirs – one hot and one cold. This machine is a nanoscale analogue of a conventional thermocouple heat-engine, in which the active region being heated is unavoidably also exchanging heat with its cold environment. Heat exchange between the dot and the thermal reservoirs is treated as a capacitive coupling to electronic fluctuations in localized levels, modeled as two additional quantum dots. The resulting multiple-dot setup is described using a master equation approach. We observe an “exotic” power generation, which remains finite even when the heat absorbed from the thermal reservoirs is zero (in other words the heat coming from the hot reservoir all escapes into the cold environment). This effect can be understood in terms of a non-local effect in which the heat flow from heat source to the cold environment generates power via a mechanism which we refer to as Coulomb heat drag. It relies on the fact that there is no relaxation in the quantum dot system, so electrons within it have a non-thermal energy distribution. More poetically, one can say that we find a spatial separation of the first-law of thermodynamics (heat to work conversion) from the second-law of thermodynamics (generation of entropy). We present circumstances in which this non-thermal system can generate more power than any conventional macroscopic thermocouple (with local thermalization), even when the latter works with Carnot efficiency.
Keywords:Quantum thermodynamics  Thermocouples  Thermoelectricity  Quantum transport  Energy harvesting  Coulomb drag
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