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Effects of Nb2O5 on thermal stability and optical properties of Er3+-doped tellurite glasses
Authors:Zhao Chun  Zhang Qin-Yuan  Pan Yue-Xiao and Jiang Zhong-Hong
Institution:Key Laboratory of Special Functional Materials and Advanced Manufacturing Technology (Ministry of Education) and Institute of Optical Communications, South China University of Technology,Guangzhou 510641,China; Key Laboratory of Special Functional Materials and Advanced Manufacturing Technology (Ministry of Education) and Institute of Optical Communications, South China University of Technology,Guangzhou 510641,China ;College of Applied Physics, South China Univ
Abstract:Er3+-doped tellurite glasses with molar compositions of xNb2O5-(14.7-x)Na2O--10ZnO--5K2O--10GeO2-- 60TeO2--0.3Er2O3 (x=0, 3, 5, 7 and 9) have been investigated for developing 1.5~μm fibre and planar amplifiers. The effects of Nb2O5 on the thermal stability and optical properties of Er3+-doped tellurite glasses have been discussed. It is noted that the incorporation of Nb2O5 (x=5) increases the thermal stability of tellurite glasses significantly. Er3+-doped niobium tellurite glasses exhibit a large stimulated emission cross-section (7.2\times 10-21- 10.7×10-21~cm2 and the gain bandwidth, FWHM×\sigmae^{\rm peak} (274\times 10-28 - 480×10-28~cm3), which are significantly higher than that of silicate and phosphate glasses. In addition, the intensity of upconversion luminescence of the Er3+-doped niobium tellurite glasses decreases rapidly with increasing Nb2O5 content. As a result, Er3+-doped niobium tellurite glasses might be a potential candidate for developing laser or optical amplifier devices.
Keywords:glasses  thermal analysis  optical materials  optical properties
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