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Er3+/Yb3+共掺的氟磷酸盐玻璃的光谱性质和热稳定性
引用本文:李涛,张勤远,赵纯,冯洲明,石冬梅,邓再德,姜中宏.Er3+/Yb3+共掺的氟磷酸盐玻璃的光谱性质和热稳定性[J].中国物理 B,2005,14(6):1250-1254.
作者姓名:李涛  张勤远  赵纯  冯洲明  石冬梅  邓再德  姜中宏
作者单位:Institute of Optical Communication Materials, South of China University of Technology Guangzhou 510640;Institute of Optical Communication Materials, South of China University of Technology Guangzhou 510640;Institute of Optical Communication Materials, South of China University of Technology Guangzhou 510640;Institute of Optical Communication Materials, South of China University of Technology Guangzhou 510640;Institute of Optical Communication Materials, South of China University of Technology Guangzhou 510640;Institute of Optical Communication Materials, South of China University of Technology Guangzhou 510640;Institute of Optical Communication Materials, South of China University of Technology Guangzhou 510640;Shanghai Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Shanghai 201800
基金项目:Supported by National Natural Science Foundation of China (50472053), Natural Science Foundation of Guangdong Prov. (04020036) and Science & technology Program of Guangzhou, Guangdong Prov. (2004Z2-D0131).
摘    要:研究了Er3+/Yb3+共掺的氟磷酸盐玻璃的光谱性质和热稳定性。应用Judd-Ofelt理论计算了玻璃的三个强度参量Ωt (t=2,4,6),计算了Er3+离子的辐射跃迁几率,荧光支效率和自发辐射几率等光谱参量。 经荧光谱测试发现掺Er3+/Yb3+共掺的氟磷酸盐玻璃的荧光半高宽可达63nm ,应用McCumber理论计算了1.53μm处的受激发射截面,可达6.85×10-21 cm2。

关 键 词:氟磷酸盐玻璃,Judd-Ofelt参数,光谱性质。
收稿时间:2004-11-05

Spectroscopic properties and thermal stability of Er3+/Yb3+-codoped fluorophosphate glasses
Li Tao,Zhang Qin-Yuan,Zhao Chun,Feng Zhou-Ming,Shi Dong-Mei,Deng Zai-De and Jiang Zhong-Hong.Spectroscopic properties and thermal stability of Er3+/Yb3+-codoped fluorophosphate glasses[J].Chinese Physics B,2005,14(6):1250-1254.
Authors:Li Tao  Zhang Qin-Yuan  Zhao Chun  Feng Zhou-Ming  Shi Dong-Mei  Deng Zai-De and Jiang Zhong-Hong
Institution:Institute of Optical Communication Materials, South of China University of Technology Guangzhou 510640; Institute of Optical Communication Materials, South of China University of Technology Guangzhou 510640;Shanghai Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Shanghai 201800
Abstract:A comprehensive study on the thermal stability and spectroscopic properties of Er3+/Yb3+-codoped Al(PO3)3-based fluorophosphate glasses have been reported for 1.5-mm fiber amplifiers in this paper. From optical absorption spectra, the Judd-Ofelt parameters of Er3+ in the glasses and then several important optical properties, i.e., the radiative transition probability, the branching ratio and the spontaneous emission probability, have been calculated by Judd-Ofelt theory. The fluorophosphate glass exhibits broadband near-infrared emission at 1.53 mm with a full width at half-maximum over 63 nm, and a large calculated stimulated-emission cross-section of 6.85×10-21 cm2.
Keywords:Fluorophosphate glasses  Judd-Ofelt parameters  Spectroscopic properties  
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