Investigation of the ozone formation process in a nanosecond microwave discharge in air and oxygen |
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Authors: | R A Akhmedzhanov A L Vikharev A M Gorbachev O A Ivanov A L Kolysko |
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Institution: | (1) Institute of Applied Physics, Russian Academy of Sciences, 603600 Nizhnii Novgorod, Russia |
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Abstract: | Results are presented from an investigation of the dynamics of ozone formation in a freely localized discharge generated by
a periodic train of 3-cm nanostructured microwave pulses in oxygen and air at a pressure p=3–30 Torr. Conditions for the efficient generation of ozone in air with the minimum production of nitrogen oxides are demonstrated
experimentally. It is shown that when the microwave pulse repetition frequency is high, heating of the gas and the buildup
of nitrogen oxides in the discharge in air reduce the ozone formation efficiency while under prolonged exposure the ozone
formed initially is destroyed. The energy cost of forming ozone in oxygen and air is determined as a function of the microwave
pulse length and repetition frequency and the gas pressure. The lowest energy cost of forming a single ozone molecule in these
experiments is 16 eV per molecule for a discharge in air and 4 eV per molecule in oxygen. It was observed that circulating
the gas through the discharge zone enhances th ozone formation efficiency. It is shown that there are optimal conditions for
ozone formation as a function of the reduced electric field in the plasma.
Zh. Tekh. Fiz. 67, 9–18 (March 1997) |
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