Infrared spectra and isomerization of CHNO species in rare gas matrices |
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| Authors: | VE Bondybey JH English CWeldon Mathews RJ Contolini |
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| Institution: | Bell Laboratories, Murray Hill, New Jersey 07974 USA;Department of Chemistry, The Ohio State University, Columbus, Ohio 43210 USA |
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| Abstract: | Infrared and uv absorption spectra of the CHNO isomers in rare gas matrices and their photolysis products by ultraviolet light were studied. The most efficient processes occurring in the matrix involve isomerization between the CHNO species. The NCO free radical is the only fragment appearing in the ir spectrum. The diatomic fragments CN, NH, and OH are also observable in the uv spectrum of photolyzed samples. |
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