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The ν6=1 state of fluoroform, HCF3: analysis of the rotational and vibrational spectra
Authors:A Ceausu-Velcescu  J Coslou  J Demaison  G Graner  G Duxbury  H Bürger
Institution:A. Ceausu-Velcescu, J. Cosléou, J. Demaison, G. Graner, G. Duxbury,H. Bürger
Abstract:An analysis of the ν6=1 state of fluoroform is performed using rotational and high resolution infrared spectra. Previously radiofrequency data Chem. Phys. Lett. 214 (1993) 265–270] and millimeter data J. Mol. Spectrosc. 131 (1988) 1–8] were combined with new millimeter and infrared measurements, and a set of 27 parameters has been derived. A multiple fit analysis was performed confirming the assumption that the ν6=1 excited state is not affected by intervibrational resonances.
Keywords:Rovibrational spectra of HCF3
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