On the Determination of the Equilibrium Structure of the PH3 Molecule

Values of the r_e and α_e equilibrium structural parameters of the PH₃ molecule have been determined on the basis of experimental data on the fundamental bands of the PH₂D and PHD₂ species only, without any knowledge of the force-constant-type parameters of the PH₃ molecule. The functions of the equilibrium rotational parameters A^e, B^e, and C^e have been determined. These functions are totally independent of the values of any resonance interaction parameters. Then these functions have been used to determine r_e and α_e constants. The obtained values r_e=(1.416 776±0.000 164) Å and α_e=(93.56±0.29)° differ a little from those found in the earlier literature.