Electronic spectrum of acetaldehyde: Vibrational analysis of the 182-nm system |
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Authors: | James S Crighton Stephen Bell |
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Institution: | Department of Chemistry, University of Dundee, Dundee DD1 4HN, U.K. |
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Abstract: | The electronic absorption spectra of CH3CHO, CH3CDO, CD3CHO, and CD3CDO have been obtained in the vacuum ultraviolet region. Vibrational analysis of the 182-nm system was made with the help of wavenumbers from their infrared spectra and also geometries and wavenumbers obtained from ab initio calculations. This system is assigned as a single Rydberg (3s ? n) electronic transition. |
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