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掺杂型BaFBr:Eu2+的热释发光性质的研究
引用本文:余华,熊光楠,朱汇,高素华,王世铭,李岩.掺杂型BaFBr:Eu2+的热释发光性质的研究[J].光学学报,2002,22(12):497-1500.
作者姓名:余华  熊光楠  朱汇  高素华  王世铭  李岩
作者单位:天津理工学院材料物理研究所,天津,300191
基金项目:国家自然科学基金(69677015),天津市科委重大攻关项目基金(013180611),天津市重点学科专项基金
摘    要:BaFBr:Eu^2 是利用色心存储电子-空穴对并用可见光激励读出存储信息(产生Eu^2 的4f^65d→4f^7的跃迁)的优良的光激励发光材料。通过热释发光技术研究了BaFBr:Eu^2 的热激活行为,对其低温段和高温段的热释发光峰分别进行了归属,通过对BaFBr:Eu^2 以及掺杂Na^ 或Al^3 的BaFBr:Eu^2 的热释发光(TL)谱和光激励发光(PSL)谱的表征,指出在BaFBr:Eu^2 中掺杂Na^ 或Al^3 影响了F(Br^-)色心,使其陷阱深度变涛,并从理论上加以计算,得出的热致激发能量的变化与光致激光能量的变化能很好地吻合。

关 键 词:BaFBr:Eu^2+  热释发光  光激励发光  色心  铕(Ⅱ)  稀土掺杂  氟溴化钡
收稿时间:2001/11/13

Property of Thermal Luminescence in BaFBr:Eu2+ Doped Metal Ions
Yu Hua Xiong Guangnan Zhu Hui Gao Suhua Wang Shiming Li Yan.Property of Thermal Luminescence in BaFBr:Eu2+ Doped Metal Ions[J].Acta Optica Sinica,2002,22(12):497-1500.
Authors:Yu Hua Xiong Guangnan Zhu Hui Gao Suhua Wang Shiming Li Yan
Abstract:BaFBr:Eu2+ is good photostimulated luminescent material, which makes use of colour center storage energy and stimulating energy with visible light. The thermal activation of BaFBr :Eu2+ is studied by thermal luminescence experiment. Through spectra of thermal luminescence (TL) and photostimulated luminescence (PSL), the phenomenon shows that doping metal ions influence F(Br- ) center in BaFBr: Eu2+ and make trap depth of F(Br- ) center shallow. A variety of F(Br ) center's trap depth of BaFBr:Eu2 + and BaFBr :Eu2+ doped metal ions is calculated in theory. The results indicate that the variety of trap depth confirm each other in thermal and photo-excitation.
Keywords:rare earth  BaFBr: Eu2+  thermal luminescence  photostimulated luminescence  colour center  
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