| 塞曼调制磁旋转激光光谱方法 |
| |
| 引用本文： | 陈金海,蔡佩佩.塞曼调制磁旋转激光光谱方法[J].光学学报,1996,16(5):12-617. |
| |
| 作者姓名： | 陈金海 蔡佩佩 |
| |
| 作者单位： | 华东师范大学物理系，中国科学院上海光学精密机械研究所，华东师范大学量子光学（联合）开放实验室 |
| |
| 基金项目： | 波谱与原子分子物理国家重点实验室资助课题,国家自然科学基金。 |
| |
| 摘 要： | 首次在可见光波段采用塞曼调制磁旋转激光光谱技术有效地将磁旋转信号（ｎ＋，－ｎ－）从激光本底以及高阶磁旋转信号中分离出来，因而有非常高的测量灵敏度与信噪比以及无吸收本底，同时又可以抑制高转动量子态的跃迁谱线，减少谱线重叠现象，非常适合许多自由基分子的测量。文中给出了这种光谱技术的理论分析，并以ＮＯ２分子作为检验对象，由理论模拟计算所得谱线的强度，线型和位相与实测结果符合较好，因此也可利用这种光谱方法
|
| 关 键 词： | 场调制 磁旋光 激光光谱 |
| 收稿时间： | 1995/5/12 |
Zeeman Modulation Magnetic Rotation Laser Spectroscopy |
| |
| Chen Jinhai,Chen Yangqin,Cai Peipei,Xia Changping Mao Wentao,Lu Feng,Wang Zugeng.Zeeman Modulation Magnetic Rotation Laser Spectroscopy[J].Acta Optica Sinica,1996,16(5):12-617. |
| |
| Authors: | Chen Jinhai Chen Yangqin Cai Peipei Xia Changping Mao Wentao Lu Feng Wang Zugeng |
| |
| Abstract: | Zeeman modulation magnetic rotation laser spectroscopy (ZM MRS) was first used to seperate the magneticc rotation signal (n +-n -) effectively from the laser background and the high order terms of magnetic rotation signal in visible region. It not only has very high sensitivity, high signal to noise ration and no absorption background and also can suppress the rotational spectrum with high quantum number for simplifying complex electronic spectra. In this paper the theoretical analysis of this technique is presented. As an example the intensity, lineshape and phase of NO 2 ZM MRS is simulated by computer. The results are fitted well with the experiment. This spectrscopic method is valuable for measuring free radicals and helpful for assignment of molecular spectrum. |
| |
| Keywords: | zeeman modulation magnetic rotation |
| 本文献已被 CNKI 维普 等数据库收录！ |
