| 两种钌配合物皮秒发光动力学过程研究 |
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| 引用本文： | 徐忠扬,王丽丽,倪泉丰,巢晖,王惠,张蕾,计亮年.两种钌配合物皮秒发光动力学过程研究[J].光学学报,2011(8):293-299. |
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| 作者姓名： | 徐忠扬 王丽丽 倪泉丰 巢晖 王惠 张蕾 计亮年 |
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| 作者单位： | 中山大学光电材料与技术国家重点实验室;中山大学化学与化工学院; |
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| 基金项目： | 国家自然科学基金(11004256); 广东省自然科学基金(9351027501000003); 中山大学光电材料与技术国家重点实验室开放课题资助课题 |
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| 摘 要： | 采用稳态发光光谱、瞬态发光动力学测量等手段,对两种钉配合物Ru(bpy)3](ClO4)2和Ru(bpy)2 HPIP](ClO4)2的发光性质进行了研究.稳态发光光谱表明Ru(bpy)2 HPIP](ClO4)2发光明显偏弱;皮秒瞬态发光动力学测量显示Ru(bpy)2 HPIP](ClO4)2的激发态弛豫过程...
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| 关 键 词： | 激光光学 瞬态发光动力学 时间分辨光谱技术 钉配合物 激发态弛豫 |
Study on Picosecond Luminescence Dynamics of [Ru(bpy)_3](ClO_4)_2 and [Ru(bpy)_2 HPIP](ClO_4)_2 |
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| Xu Zhongyang Wang Lili Ni Quanfeng Chao Hui Wang Hui Zhang Lei Ji Liangnian, State Key Laboratory of Optoelectronic Materials , Technologies,Sun Yat-Sen University,Guangzhou,Guangdong ,China Institute of Chemistry , Chemical Engineering,China.Study on Picosecond Luminescence Dynamics of [Ru(bpy)_3](ClO_4)_2 and [Ru(bpy)_2 HPIP](ClO_4)_2[J].Acta Optica Sinica,2011(8):293-299. |
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| Authors: | Xu Zhongyang Wang Lili Ni Quanfeng Chao Hui Wang Hui Zhang Lei Ji Liangnian State Key Laboratory of Optoelectronic Materials Technologies Sun Yat-Sen University Guangzhou Guangdong China Institute of Chemistry Chemical Engineering China |
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| Institution: | Xu Zhongyang1 Wang Lili1 Ni Quanfeng1 Chao Hui2 Wang Hui1 Zhang Lei1 Ji Liangnian1,2 1 State Key Laboratory of Optoelectronic Materials and Technologies,Sun Yat-Sen University,Guangzhou,Guangdong 510275,China2 Institute of Chemistry and Chemical Engineering,China |
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| Abstract: | The luminescence properties of two kinds of ruthenium complexes,Ru(bpy)3](ClO4)2 and Ru(bpy)2HPIP](ClO4)2,are studied by steady-state and transient emission spectroscopy.The steady-state luminescence spectrum shows that Ru(bpy)2HPIP](ClO4)2 has a weaker luminescence intensity.And the transient emission spectrum exhibits that there is a fast component within the excited-state relaxation of Ru(bpy)2HPIP](ClO4)2,which may be due to the hydrogen-bonding between metal-ligand-charge-transfer(MLCT) state and s... |
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| Keywords: | laser optics transient luminescence time-resolved spectroscopy ruthenium complexes excited-state relaxation |
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