| [Mo3S7]分子簇和聚合簇合物的振动光谱和电子光谱 |
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| 引用本文： | 陈进,余荣民.[Mo3S7]分子簇和聚合簇合物的振动光谱和电子光谱[J].光谱学与光谱分析,2000,20(6):849-851. |
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| 作者姓名： | 陈进 余荣民 |
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| 作者单位： | 结构化学国家重点实验室,中国科学院福建物质结构研究所,福建 |
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| 摘 要： | 本文报道了分立簇「Ｍｏ３Ｓ７（ｄｔｐ）３Ｉ」１及它的四聚物｛「Ｍｏ３ＳＵ（ｄｔｐ）３」４Ｉ｝．｛（ＨｇＩ３）４．Ｋ｝２（ｄｔｐ＝Ｓ２Ｐ（ＯＣ２Ｈ５）＾－２的ＩＲ，Ｒａｍａｎ和ＵＶ－Ｖｉｓ光谱，并讨论分立的「Ｍｏ３Ｓ７（ｄｔｐ）３Ｉ」在四聚后这些光谱的变化。
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| 关 键 词： | 三核钼簇合物 振动光谱 电子光谱 Mo3S7分立簇 |
Vibrational and electronic spectra of a discrete and a tetramer containing [Mo3S7] core] |
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| J Chen,R Yu,S Lu.Vibrational and electronic spectra of a discrete and a tetramer containing [Mo3S7] core][J].Spectroscopy and Spectral Analysis,2000,20(6):849-851. |
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| Authors: | J Chen R Yu S Lu |
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| Institution: | State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, 350002 Fuzhou. |
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| Abstract: | In this paper, the IR, Raman and UV-Vis spectra of a discrete cluster Mo3S7(dtp)3I]1 and its tetramer Mo3S7(dtp)3]4I].(HgI3)4].K]2(dtp = S2P(OC2H5)2-) were reported. The spectral characteristics of the compounds were discussed. According to the results of the studies on the structure and spectra, it was the weak intermolecular interaction and electrons transfer after tetramerization that led to the variation in the electronic structure of the compounds. |
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