| 2—溴甲基萘荧光和室温磷光性质研究 |
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| 引用本文： | 牟兰,陈小康.2—溴甲基萘荧光和室温磷光性质研究[J].光谱学与光谱分析,1999,19(6):880-883. |
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| 作者姓名： | 牟兰 陈小康 |
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| 作者单位： | 贵州大学化学系 |
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| 摘 要： | 研究了２－溴甲基萘（２－ＢｒＭＮ）的荧光及磷光性质。２－溴甲基萘是一种优良的荧光试剂，λｅｘ／λｅｍ＝２７４／３３４ｎｍ，其浓度在１．０×１０＾－６～１．２×１０＾－４ｍｏｌ·Ｌ＾－１范围内与荧光强度呈良好的线性关系，相关系数ｒ＝０．９９９，最低检测限为４．７×１０＾－８ｍｏｌ·Ｌ＾－１。以β－环糊精（β－ＣＤ）作保护剂和１，２－二溴丙烷（ＤＢＰ）为重原子微扰剂的２－ＢｒＭＮ／β－ＣＤ／ＤＢＰ体系
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| 关 键 词： | 溴甲基萘 荧光 室温磷光 RTP |
Study on Properties of Fluorescence and Room Temperature Phosphorescence of 2 Bromomethyl Naphthalene |
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| L Mou,X Chen,L Li.Study on Properties of Fluorescence and Room Temperature Phosphorescence of 2 Bromomethyl Naphthalene[J].Spectroscopy and Spectral Analysis,1999,19(6):880-883. |
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| Authors: | L Mou X Chen L Li |
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| Institution: | Dept. of Chem., Guizhou University, 550025 Guiyang. |
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| Abstract: | The properties of fluorescence and room temperature phosphorescense (RTP) of 2-Bromomethyl naphthalene (2-BrMN)were studied. The results show that the wavelength for maximum fluorescence of 2-BrMN is lambda(ex/lambda(em) = 274/334 nm. The fluorescence intersity is proportional to the concentration of 2BrMN in the range of 1.0 x 10(-6) - 1.2 x 10(-4) mol x L(-1), and the detection limit is 4.7 x 10(-8) mol x L(-1). The RTP signal of 2-BrMN was induced by beta-cyclodextrin (beta-(CD) in the presence of dibromopropane (DBP) acting as a heavy atom perturbation. The RTP intensity is linear for 2-BrMN/beta-CD/DBP systems of 2-BrMN concentration in the range of 1.0 x 10(-5) - 1.2 x 10(-4) mol x L(-1) (lambda(ex)/lambda(em) = 271/493,521 nm), and the detection limit is 2.7 x 10(-6) mol x L(-1). |
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| Keywords: | Bromomethyl naphthalene Fluorescence Room temperature phosphorescence |
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