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胆红素—氟化钡体系固相研磨反应的红外光谱研究
引用本文:杨殿澜,翁诗甫.胆红素—氟化钡体系固相研磨反应的红外光谱研究[J].光谱学与光谱分析,1998,18(2):187-190.
作者姓名:杨殿澜  翁诗甫
作者单位:北京大学化学与分子工程学院
摘    要:本文利用红外光谱法对胆红素-氟化钡体系的固相研磨反应进行了研究。结果表明,该固相研磨反应具有氧参加的自由基反应机制,并且反应产物中胆红素与钡离子的络合形式五液相反应合成的胆红素钡络合物不同。

关 键 词:胆红素钡  固相反应  结石  色素型  胆红素配合物

FT IR STUDY ON THE SOLID STATE REACTION OF BILIRUBIN ON BaF 2
Abstract:Bilirubinate complexes are the main component of pigment gallstones and the recent researches suggested that bilirubin free radical plays a role in some biological processes.In this paper the solid state reaction of bilirubin on BaF 2 was examined by FT IR.The solid state reaction was produced by grinding the crystalline bilirubin and single crystals BaF 2 together in an agate mortar.From the results the free radical mechanism is suggested in the solid state reaction of bilirubin on BaF 2.The replacement of H on NH of pyrrole by Ba 2+ was prior to that of H on COOH.The sturcture of the resultant complex from the solid state reaction is different compared with that from the liquid state reaction.
Keywords:Bilirubin    Ba bilirubinate    Solid  state reaction    FT  IR spectroscopy    Free radical  
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