| （CX3）2Y型分子的内旋转势能函数 |
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| 引用本文： | 许宗荣,高艳玲.（CX3）2Y型分子的内旋转势能函数[J].光谱学与光谱分析,1997,17(1):25-28. |
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| 作者姓名： | 许宗荣 高艳玲 |
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| 作者单位： | 成都科技大学原子分子科学所 |
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| 摘 要： | 研究有Ｍ（≥２）个等价的Ｎ（≥３）重对称内旋转陀螺的分子，将内旋运动方程解耦，应用无波函数微扰理论，导出内旋转能谱解析式，应用所得结果及扭转频率的光谱数据，确定了（ＣＨ３）２Ｏ与（ＣＦ３）２ＣＯ分子的内旋转势能函数。
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| 关 键 词： | 内旋转势函烽 CX3Y型 分子 |
POTENTIAL ENERGY FUNCTION OF INTERNAL ROTATION FOR THE MOLECULES OF (CX 3) 2Y TYPE |
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| Z Xu,Y Gao.POTENTIAL ENERGY FUNCTION OF INTERNAL ROTATION FOR THE MOLECULES OF (CX 3) 2Y TYPE[J].Spectroscopy and Spectral Analysis,1997,17(1):25-28. |
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| Authors: | Z Xu Y Gao |
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| Institution: | Chengdu University of Science and Technology, 610065 Chengdu. |
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| Abstract: | Studing on the molecules having M -tops of N -fold symmetries, decoupling the equation of motion for rotation and using the perturbation theory without wave function, the formula of the energies of internal rotation has been derived and the potential energy functions of internal rotation for (CH3)2O and (CF3)2CO have been determined. |
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| Keywords: | Potential energy function of internal rotation (CH 3) 2O (CF 3) 2CO |
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