| 单（6—S—丹磺酰基）—β—环糊精的合成及其分子识别功能初探 |
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| 引用本文： | 朱渝萍,李隆弟.单（6—S—丹磺酰基）—β—环糊精的合成及其分子识别功能初探[J].光谱学与光谱分析,1997,17(2):15-19. |
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| 作者姓名： | 朱渝萍 李隆弟 |
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| 作者单位： | 清华大学化学系 |
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| 摘 要： | 合成鉴定具有发光基团的环糊精衍生物，研究了该产物水溶液的荧光特性和它对客体环己醇，环己烯，溴化环己烷，以及苯甲酸系列的包结与识别作用，用修正的Ｈｉｌｄｅｂｒａｎｄ－Ｂｅｎｅｓｉ方程计算得主客化合物的包结常数和识别因子，不仅证明主客体间形成１：１包结物，且其包结常数和识别因子与客体的分子结构及疏水性等直接有关。
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| 关 键 词： | 丹磺酰基 环糊精 合成 分子识别功能 |
The synthesize of mono-( 6-S-DNS )- beta-CD and its molecular recognition ability] |
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| Y Zhu,L Li,A Tong.The synthesize of mono-( 6-S-DNS )- beta-CD and its molecular recognition ability][J].Spectroscopy and Spectral Analysis,1997,17(2):15-19. |
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| Authors: | Y Zhu L Li A Tong |
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| Institution: | Department of Chemistry, Tsinghua University, 100084 Beijing. |
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| Abstract: | Mono- ( (6-S-DNS) - beta -CD is synthesized and characterized. The interaction between the luminescent derivative of beta-cyclodextrin and guest (cyclohexanol, cyclohexene, Bromocyclohexane, and p-phthalic acid, m-phthalic acid 3, 5-Dinitrobenzoic acid, p-hydroxybenzoic acid, p-animobenzoic acid)has been slutied. The binding constants and sensitivety factors are obtained based on modified Hildbrand-Benesi equation. The results show that the guest-Host inclusion complex with 1:1 stoichiometry is formed and that the binding constants and sensitivity factors for molecular recognition is directly related to the molecular structure and hydrophobic character of guest. |
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