| 法拉第参数对几种四苯基卟啉金属络合物MCD谱的影响 |
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| 引用本文： | 郭瑞云,胡靖.法拉第参数对几种四苯基卟啉金属络合物MCD谱的影响[J].光谱学与光谱分析,1993,13(5):47-50,46. |
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| 作者姓名： | 郭瑞云 胡靖 |
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| 作者单位： | 河南化学研究所，河南化学研究所，河南化学研究所，河南化学研究所，中科院兰州化学物理所 450003 郑州，450003 郑州，450003 郑州，450003 郑州，730000 兰州 |
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| 摘 要： | 本文测量了四苯基卟啉铁（ＦｅＴＰＰＣｌ），四苯基卟啉钴（ＣｏＴＰＰ）和四苯基卟啉镍（ＮｉＴＰＰ）的紫外可见吸收光谱和磁圆二色谱（ＭＣＤ），讨论了法拉第参数Ａ，Ｂ两项对Ｓｏｒｅｔ带和Ｑ带的综合影响。发现Ｂ项有参与且使ＭＣＤ谱中Ａ项的Ｓ曲线与波长λ轴交点的跃迁波长值较紫外可见光谱有红移和蓝移的特征。
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| 关 键 词： | 法拉第参数 卟啉 金属络合物 MCD谱 |
EFFECT OF THE FARADAY PARAMETERS ON THE MCD SPECTRA OF METALLOPORPHYRIN |
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| GUO Ruiyun,CHANG Junbiao,LIN Sufeng and CHENG Rongfeng Henan Institute of Chemistry, Zhengzhou HU Jing Lanzhou Institute of Chemical Physics,Academia Sinica, Lanzhou.EFFECT OF THE FARADAY PARAMETERS ON THE MCD SPECTRA OF METALLOPORPHYRIN[J].Spectroscopy and Spectral Analysis,1993,13(5):47-50,46. |
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| Authors: | GUO Ruiyun CHANG Junbiao LIN Sufeng and CHENG Rongfeng Henan Institute of Chemistry Zhengzhou HU Jing Lanzhou Institute of Chemical Physics Academia Sinica Lanzhou |
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| Institution: | GUO Ruiyun,CHANG Junbiao,LIN Sufeng and CHENG Rongfeng Henan Institute of Chemistry,45000 Zhengzhou HU Jing Lanzhou Institute of Chemical Physics,Academia Sinica,730000 Lanzhou |
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| Abstract: | The UV and MCD spectra of FeTPPCI. CoTPP, NiTPP were reported and the effect of Faraday parameters A, B on Sorer band and Q band were discussed. It was found that the parameter B had an influence in MCD spectra and made the point of interseclion of the S shape of A and wavelength red or blue shift against the transiton wavelength in UV spectra. |
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| Keywords: | Magnetic circular dichroism (MCD) Ultraviolet spectra (UV) Faraday parameter Metalloporphyin |
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