| 新型L-氨基酸尾式卟啉及其锌(Ⅱ)配合物的合成与光谱性质 |
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| 引用本文： | 罗国添,滕莉丽,赖晓绮,李蕾.新型L-氨基酸尾式卟啉及其锌(Ⅱ)配合物的合成与光谱性质[J].光谱学与光谱分析,2004,24(2):173-176. |
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| 作者姓名： | 罗国添 滕莉丽 赖晓绮 李蕾 |
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| 作者单位： | 赣南师范学院化学与生命科学系,江西,赣州,341000 |
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| 基金项目： | 江西省教育厅科技计划课题 ( 2 0 0 2 0 110 )资助 |
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| 摘 要： | 用L 氨基酸和 5 邻 (2 溴乙氧基 )苯基 ] 1 0 ,1 5 ,2 0 三苯基卟啉为原料合成了三种新型L 氨基酸尾式卟啉及其锌 (Ⅱ )配合物 ,通过元素分析、红外光谱、紫外光谱、化学分析和质谱等对其进行了结构表征。测试并研究了它们在 4 0 0 0～ 4 0 0cm-1 范围内的傅里叶变换红外光谱 ,对主要谱带进行了经验归属
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| 关 键 词： | L-氨基酸尾式卟啉 锌(Ⅱ)配合物 合成 光谱性质 |
| 文章编号： | 1000-0593(2004)02-0173-04 |
| 修稿时间： | 2002年12月9日 |
Synthesis and Spectral Properties of L-Amino Acid Tailed Porphyrin and Their Zinc(Ⅱ) Complexes |
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| LUO Guo tian,TENG Li li,LAI Xiao qi,LI Lei.Synthesis and Spectral Properties of L-Amino Acid Tailed Porphyrin and Their Zinc(Ⅱ) Complexes[J].Spectroscopy and Spectral Analysis,2004,24(2):173-176. |
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| Authors: | LUO Guo tian TENG Li li LAI Xiao qi LI Lei |
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| Institution: | Department of Chemistry and Life Science, Gannan Teachers' College, Ganzhou 341000, China. |
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| Abstract: | Three new L-amino acid tailed porphyrins and their zinc(II) complexes were synthesized by L-amino acid and 5-o-(bromnoethoxyl)phenyl]-10,15,20-triphenyl prophyrin. FABMS, UV-Vis, IR, elemental analysis and chemical analysis were used to determine the structures of these porphyrins and their zinc complexes. The FTIR spectra (4000-400 cm(-1)) of L-amino acid tailed porphyrin and its zinc(II) complexes were measured and investigated. The major bands have been empirically assigned in comparison with L- amino acid tailed porphyrin and its zinc(II) complexes. |
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