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小波分解重建算法提高近红外煤质水分检测精度
引用本文:贾浩,付强,韩婵娟,邹德宝,陈文亮,徐可欣.小波分解重建算法提高近红外煤质水分检测精度[J].光谱学与光谱分析,2012,32(11):3010-3013.
作者姓名:贾浩  付强  韩婵娟  邹德宝  陈文亮  徐可欣
作者单位:1. 天津大学精密测试技术及仪器国家重点实验室,天津 300072
2. 天津市津南区环保监测站,天津 300350
3. 天津大学环境科学与工程学院,天津 300072
4. 天津大学微光机电系统技术教育部重点实验室,天津 300072
基金项目:国家自然科学重点基金项目,天津市自然科学基金重点项目
摘    要:水分是煤质经济价值的基本指标,会造成煤质利用率下降和能源浪费。因此,近红外光谱法实现煤质水分快速、无损、低成本检测具有重要意义。针对目前近红外煤质水分检测精度普遍在1%,且鲜有关于精度提高系统性研究的现状,从光谱预处理及波长选择进行比较,提出了提高煤质水分检测精度的可行性方法。实验结果表明,采用小波分解重建算法对1 300~2 400 nm光谱区间进行降噪及去基线预处理,对重建光谱进行偏最小二乘建模,其建模结果明显优于其他方法,RMSEC达到0.06%,RMSEP达到0.27%,相关性系数R-square达到0.995,且证明模型稳定性较好,显著提高了近红外煤质水分的检测精度。

关 键 词:近红外光谱  小波分解重建  偏最小二乘法  
收稿时间:2012-05-17

Improving Precision in Coal Moisture Detection Using Wavelet Transform
JIA Hao , FU Qiang , HAN Chan-juan , ZOU De-bao , CHEN Wen-liang , XU Ke-xin.Improving Precision in Coal Moisture Detection Using Wavelet Transform[J].Spectroscopy and Spectral Analysis,2012,32(11):3010-3013.
Authors:JIA Hao  FU Qiang  HAN Chan-juan  ZOU De-bao  CHEN Wen-liang  XU Ke-xin
Institution:1. State Key Laboratory of Precision Measuring Technology and Instruments, Tianjin University, Tianjin 300072, China2. Environment Monitoring Station of Jinnan District, Tianjin 300350, China3. School of Environment Science and Engineering, Tianjin University, Tianjin 300072, China4. Key Laboratory of Micro-Optical-Electro-Mechanical System Technology (Tianjin University), Ministry of Education, Tianjin 300072, China
Abstract:Moisture, as a core determination of the economic value of coal, can result in the utilization and energy inefficiency. Near-infrared (NIR) spectroscopy, with advantages of high accuracy and low cost, provides significant solution to the quick and non-invasive detection of coal moisture. In the present paper, the improvement of the coal moisture analysis was conducted based on the precision of 1% and insufficient comparisons in recent experiments, and aspects of spectrum pretreatment and wavelength selection were mainly discussed. The optimized result with R-square of 0.995, RMSEC of 0.06% and RMSEP of 0.27% indicates the priority of wavelet decomposition and reconstruction, compared with other methods, in the noise reduction and baseline removing of original spectra (1 300~2 400 nm) before PLS modeling, and the stability experiment validates its robust potential in improving precision of coal moisture detection based on the NIR spectroscopy.
Keywords:Near-infrared spectroscopy  Wavelet decomposition and reconstruction  Partial least square (PLS) modeling  
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