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高分辨分子吸收光谱中的波长校准方法
引用本文:吴升海,庄华,杨晓华,刘煜炎,陈扬駸.高分辨分子吸收光谱中的波长校准方法[J].光谱学与光谱分析,2002,22(4):569-572.
作者姓名:吴升海  庄华  杨晓华  刘煜炎  陈扬駸
作者单位:华东师范大学光谱与波谱教育部重点实验室,上海,200062;华东师范大学物理系,上海,200062
基金项目:国家自然科学基金 (批准号199740 11),波谱学和原子分子物理国家重点实验室基金 (批准号 :991516)资助项目
摘    要:本文提出高分辨分子吸收光谱中,以碘分子谱作为参考标准的波长校准方法,编制了以人机交互方式自动完成波长校准的软件,并应用于16 422-17 896cm^-1可见光波段范围内的N2^ 分子离子的高分辨吸收谱线的波长校准,结果表明其绝对准确度可达0.006cm^-1。

关 键 词:波长  校准方法  高分辨分子吸收光谱
文章编号:1000-0593(2002)04-0569-04
修稿时间:2001年6月22日

The Method of Wavelength Calibration in High Resolution Absorption Spectroscopy
Sheng-hai Wu,Hua Zhuang,Xiao-hua Yang,Yu-yan Liu,Yang-qin Chen.The Method of Wavelength Calibration in High Resolution Absorption Spectroscopy[J].Spectroscopy and Spectral Analysis,2002,22(4):569-572.
Authors:Sheng-hai Wu  Hua Zhuang  Xiao-hua Yang  Yu-yan Liu  Yang-qin Chen
Institution:Key Laboratory for Optical and Magnetic Resonance Spectroscopy, Department of Physics, East China Normal University, Shanghai 200062, China.
Abstract:A new method for the calibration of wavelength in a measurement of high resolution molecular absorption spectra by referring the standard spectrum of iodine molecule is presented in this paper Segment offset is employed in the calibration of wavelength, while the data smoothing, baseline determining and peak fitting are applied to preprocess the spectral data A visual software is provided for automatically calibrating wavelength with a friendly style of mutual dialogue between human and computer The software has been used to calibrate the absorption spectra of N + 2 molecular ion in the visible region 16 422-17 896 cm -1 , the absolute accuracy is about 0 006 cm -1
Keywords:Calibration of wavelength  High resolution absorption spectra  
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