| 磺酸基对掺杂酞菁在溶胶-凝胶复合体系中UV/Vis吸收光谱的影响 |
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| 引用本文： | 詹红兵,杜育红,林春莺,赵旭成,秦静.磺酸基对掺杂酞菁在溶胶-凝胶复合体系中UV/Vis吸收光谱的影响[J].光谱学与光谱分析,2005,25(11):1850-1852. |
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| 作者姓名： | 詹红兵 杜育红 林春莺 赵旭成 秦静 |
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| 作者单位： | 福州大学材料学院，福建 福州 350002 |
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| 基金项目： | 国家自然科学基金（50472001）,教育部和福建省教育厅科研重点支持项目（JA03001）资助 |
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| 摘 要： | 选择、设计具有代表性无取代酞菁镍(NiPc)和周环带有4个磺酸基的四磺化酞菁镍(NiTSPc)，采用溶胶-凝胶湿化学将其均匀掺入SiO2凝胶基质，制备无机基质酞菁掺杂复合光功能材料并考察磺酸基的引入对掺杂酞菁在溶胶-凝胶复合体系中UV/Vis吸收光谱的影响。研究结果表明水溶性磺酸基的引入有助于改善酞菁的溶解性，进而实现其与溶胶-凝胶体系的稳定互溶，使酞菁均匀掺杂复合材料的制备成为可能。
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| 关 键 词： | 酞菁掺杂 磺酸基 溶胶-凝胶复合体系 UV/Vis吸收光谱 |
| 文章编号： | 1000-0593（2005）11-1850-03 |
| 收稿时间： | 2004-06-18 |
| 修稿时间： | 2004-08-28 |
Influence of Tetrasulfo-Substituents on the UV/Vis Absorption Spectra of Phthalocyanine Doped Sol-Gel Hybrid |
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| ZHAN Hong-bing,DU Yu-hong,LIN Chun-ying,ZHAO Xu-cheng,QIN Jing.Influence of Tetrasulfo-Substituents on the UV/Vis Absorption Spectra of Phthalocyanine Doped Sol-Gel Hybrid[J].Spectroscopy and Spectral Analysis,2005,25(11):1850-1852. |
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| Authors: | ZHAN Hong-bing DU Yu-hong LIN Chun-ying ZHAO Xu-cheng QIN Jing |
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| Institution: | College of Materials Science and Engineering, Fuzhou University, Fuzhou 350002, China |
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| Abstract: | Nickle phthalocyanine(NiPc) and Nickle tetrasulfo-phthalocyanine(NiTSPc) were introduced respectively into silica gel matrix by sol-gel technique.Composites were produced and their UV/Vis spectra were measured.The results show that the introduction of soluble tetrasulfo-substituents can greatly increase the solubility of phthalocyanine molecule,which is helpful for the steady co-existence of phthalocyanine in sol-gel hybrid and therefore beneficial to the production of homogeneous composite. |
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| Keywords: | Phthalocyanine doped Tetrasulfo-substituents Sol-gel hybrid UV/Vis absorption spectra |
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