激光诱导等离子体光谱法(LIPS)测定不锈钢中微量元素

激光诱导等离子体光谱技术(LIPS)是一种非接触式实时检测技术,将其用于对钢铁成分检测,可满足大型钢铁企业高速化、连续化、自动化生产要求。以波长为1064nm的Nd∶YAG调Q固体激光器为激发光源,ICCD为探测器,标准不锈钢1Cr18Ni9Ti系列为样品在建立的LIPS实验装置上对样品中微量金属元素铝、锰、钴、钼和钛的含量进行了测量。实验中通过对ICCD工作的延迟时间和积分时间的合理设置得到高信噪比的谱线信号,在光谱数据处理时采用了基于基体效应的内标法。实验结果显示,测量元素的浓度与定标元素铁的浓度之比与它们的谱线强度之比均呈很好的线性关系,测试的五种微量元素探测极限不大于150μg.g-1。

Determination of Minor Elements in Stainless Steel by Laser-Induced Plasma Spectroscopy (LIPS)

Laser-induced plasma spectroscopy (LIPS) is characterized by its non-contact and real-time analysis. Its application to the determination of steel composition can meet the need of high-speed, continuous and automatic production in large steel companies. In the present article the minor elements concentrations of aluminum, manganese, cobalt, molybdenum, and titanium in a series of stainless steel 1Cr18Ni9Ti samples were determinate by laser-induced plasma spectroscopy, based on a Nd : YAG Q-switched solid laser with wavelength 1 064 nm as an exciting source and ICCD as detector. In the experiment the working delay time and gate time of ICCD were set suitably to get high signal-to-noise ratio emission spectral lines, and the internal standardization method related to matrix effect was used to deal with spectral data. Experiment results show that the concentration ratios of all the measured elements versus the reference element ferrum have a good linear relationship with the intensity ratios of them, the detection limits of the five tested elements are within 150 microg x g(-1).