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MEH-PPV/ZnO纳米晶无机有机复合电致发光器件的研究
引用本文:李海玲,王永生,滕枫,徐征.MEH-PPV/ZnO纳米晶无机有机复合电致发光器件的研究[J].光谱学与光谱分析,2004,24(10):1172-1175.
作者姓名:李海玲  王永生  滕枫  徐征
作者单位:北京交通大学光电子技术研究所,信息存储、显示与材料开放实验室,北京,100044;北京交通大学光电子技术研究所,信息存储、显示与材料开放实验室,北京,100044;北京交通大学光电子技术研究所,信息存储、显示与材料开放实验室,北京,100044;北京交通大学光电子技术研究所,信息存储、显示与材料开放实验室,北京,100044
基金项目:教育部高校优秀青年教师奖励计划,“973”计划项目 (2 0 0 3CD31 4 70 7)资助
摘    要:以Ⅱ一Ⅵ族无机半导体ZnO纳米颗粒为电子传输层,MEH-PPV为空穴传输层兼发光层,得到的电致发光器件比单层MEH-PPV器件的发光亮度和效率都明显提高。器件结构为ITO/MEH-PPV/ZnO/Al的电致发光光谱同单层PPV器件的光谱出现了不同,在620nm处出现了一个小的发光峰,应该是ZnO的发光。另外,双层结构器件的启亮电压由单层器件的9V降到了4V左右。由I-V曲线及发光光谱可判断出发光区域应在MEH-PPV/ZnO界面处,并且复合区域可能随着电压的变化而变化。

关 键 词:异质结  电致发光  聚合物  ZnO纳米颗粒
文章编号:1000-0593(2004)10-1172-04
修稿时间:2003年1月6日

Electroluminescence Property of MEH-PPV/ZnO Nano-Crystal Structure
LI Hai-ling,WANG Yong-sheng,TENG Feng,XU ZhengInstitute of Optoelectronic Technology Beijing Jiaotong University,Key Lab of Material for Information Storage and Display,Beijing ,China.Electroluminescence Property of MEH-PPV/ZnO Nano-Crystal Structure[J].Spectroscopy and Spectral Analysis,2004,24(10):1172-1175.
Authors:LI Hai-ling  WANG Yong-sheng  TENG Feng  XU ZhengInstitute of Optoelectronic Technology Beijing Jiaotong University  Key Lab of Material for Information Storage and Display  Beijing  China
Institution:Institute of Optoelectronic Technology Beijing Jiaotong University, Key Lab of Material for Information Storage and Display, Beijing 100044, China.
Abstract:A new structure with II-VI nano-crystal ZnO film as the electron transport layer and MEH-PPV as the hole transport layer and emitting layer was fabricated. The new structure's brightness and efficiency were improved markedly compared with that of the single MEH-PPV layer structure. And a new peak at 620 nm was found in the ITO/MEH-PPV/ZnO/Al structure's electroluminescence spectrum, which should resulted from ZnO layer. In addition, the turning-on voltage of the two-layer structure decreased from 9 V of the single layer structure to 4 V. From the I-V curve, the authors concluded that the emitting area was around the interface of MEH-PPV/ZnO and the combination area could shift with changing the voltage.
Keywords:Heterojunction  Electroluminescence  Polymer  ZnO nanoparticles
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