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pr3+掺杂透明氟氧化物玻璃陶瓷的光谱特性
作者姓名:Chen Y  Chen XB  Chen L  Yang XD  Hu LL  Wu ZL  Yu CL  Wang YF  Liu DH  Tian Q
作者单位:1. 北京师范大学物理系,应用光学北京重点实验室,分析测试中心,北京100875
2. 中国科学院上海高功率激光玻璃研究中心,上海,201800
基金项目:国家自然科学基金项目(10674019)资助
摘    要:根据pr3+掺杂透明氟氧化物玻璃陶瓷(Pr(0.2)∶FOV)样品在室温下的吸收光谱,分别采用了标准和修正的Judd-Ofelt理论拟合出J-O强度三参量Mn.结果表明,此修正的J-O理论应用到Pr(0.2):FOV材料的跃迁强度计算中是合理的和必要的.并由此修正理论计算了各个激发态之间跃迁的振子强度、自发辐射速率、荧...

关 键 词:Pr3+掺杂氟氧化物玻璃陶瓷  修正的J-O理论  光谱特性

Spectroscopic properties of Pr3+ doped transparent oxyfluoride vitroceramics
Chen Y,Chen XB,Chen L,Yang XD,Hu LL,Wu ZL,Yu CL,Wang YF,Liu DH,Tian Q.Spectroscopic properties of Pr3+ doped transparent oxyfluoride vitroceramics[J].Spectroscopy and Spectral Analysis,2011,31(12):3213-3217.
Authors:Chen Ying  Chen Xiao-bo  Chen Luan  Yang Xiao-dong  Hu Li-li  Wu Zheng-long  Yu Chun-lei  Wang Ya-fei  Liu Da-he  Tian Qiang
Institution:CHEN Ying1,CHEN Xiao-bo1,CHEN Luan1,YANG Xiao-dong1,HU Li-li2,WU Zheng-long1,YU Chun-lei2,WANG Ya-fei1,LIU Dah e 1,TIAN Qiang1 1.Department of Physics,Applied Optics Beijing Area Major Laboratory,Analytical and Testing Center,Beijing Normal University,Beijing 100875,China 2.Shanghai Research Center of High Power Laser Glass,Chinese Academy of Sciences,Shanghai 201800,China
Abstract:In the present paper, the room-temperature absorption spectrum of Pr+ -doped transparent oxyfluoride vitroceramics (Pr(0.2):FOV) was studied systematically. The optical characterisation of Pr(0.2):FOV was performed. The standard and modified Judd-Ofelt theories were used to determine the J-O intensity parameters. The problems with standard Judd-Ofelt theorie for Pr3+ were discussed. Based on the intensity parameters, some predicted optical parameters, such as the spontaneous radiative transition probabilities, radiative lifetimes, branching ratios and integrated emission cross section were calculated. And the application of Pr:FOV was analyzed. Especially there are large oscillator strength and large integrated emission cross section in the transitions of (3)P0-->(3)H4, (3)P1-->(3)H5 and (3)P0-->(3)H6, (3)P0-->(3)F2. So, they are more worthy of attention. The obtained spectroscopic results show the potential application of the Pr3+ -doped oxyfluoride vitroceramics for solid-state lasers.
Keywords:Pr3 -doped oxyfluoride vitroceramics  Modified Judd-Ofelt theories  Spectroscopic properties  
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