毛竹化学成分光谱分析的快速建模方法研究

研究了毛竹综纤维素和木质素含量近红外光谱定量分析方法的建立。选用不同竹龄、纵向和横向部位的54个竹材粉末样品，用湿化学方法测定其综纤维素和木质素含量。在综纤维素和木质素含量的分布范围内，从低值、中间值和高值中挑选11个代表性样品，11个样品按预定比例混合得到21个混合样品，混合样品的综纤维素和木质素含量计算得到，再挑选22个目标成分含量不同的样品组成54个样品的校正集。用偏最小二乘法分别建立样品综纤维素含量、木质素含量和近红外漫发射光谱之间的相关模型。结果表明，综纤维素含量的预测模型的相关系数（Rp）为0.92，标准偏差（SEP）为1.04％;木质素含量的预测模型的Rp为0.93，SEP为0.91％，与常规方法建立的模型预测精度相似。说明利用样品混合的方式可快速增加校正集样品的数量、改善校正集样品的分布状况，继而建立稳定可靠的近红外定量分析模型。

Rapid Modeling Method for Spectroscopic Analysis of Chemical Components of Bamboo

A rapid modeling method for predicting the chemical components contents of bamboo was presented.The holocellulose contents and lignin contents of 54 samples from three growth years,two longitudinal positions and three radial positions were analyzed according to traditional chemical methods.Eleven samples were selected based on their holocellulose content and lignin content from these 54 samples to cover the range of holocellulose content and lignin content.Eleven samples were mixed at preset ratio with each...