梯度固化聚氨酯脲中氢键的红外光谱分析

聚氨酯脲弹性体中的氢键可以反映其内部的微相分离状态，并对材料的宏观性能有着比较重要的影响。 通过梯度固化的方法制得了微相分离程度沿厚度方向梯度渐变的聚氨酯脲弹性体。 利用傅里叶变换红外光谱(FTIR)研究了梯度聚氨酯脲弹性体中的氢键，分析了羰基、亚氨基以及醚氧键的氢键，对弹性体的微相分离程度进行了表征。 结果表明，羰基区的氢键化程度随固化温度的升高而升高，表明微相分离程度的逐渐升高。 醚氧键氢键化程度随固化温度改变有差异，亚氨基的氢键化程度在交联较低的试样中随固化温度的升高而升高，在交联程度较高的试样中则相反。 脲羰基形成的三维氢键的强度比醚氧键形成的氢键强。 氢键化醚氧键的振动吸收大约位于1 076 cm-1。

Analysis of Hydrogen Bondings in Polyurethane Urea Cured in Graded Temperature Field by FTIR

Hydrogen bondings in polyurethane urea elastomer, which reflect the microphase separation, have an important effect on the properties of the elastomer. The polyurethane urea elastomers, whose degree of microphase separation changed gradually, were prepared in the graded temperature field. Hydrogen bondings in them were investigated by FTIR technology. The discussions about C=O, NH, and -O- stretching vibration spectra were given. The percentage of hydrogen bonded carbonyl groups increases with the increase in the curing temperature in the thickness direction, which indicates the increase in the degree of microphase separation in it. The degree of hydrogen bonded ether oxygen atoms exhibits obvious difference in polyurethane urea with different crosslinking degree. It is this difference that leads to a contrast changing trend of the percentage of hydrogen bonded NH in different samples. Three-dimensional hydrogen bonding between urea carbonyl and NH is stronger than the hydrogen bonding between ether oxygen atoms and NH. The stretching vibration of hydrogen bonded ether group is at about 1 076 cm(-1).