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6种不同取代基的双吖啶类探针的化学发光性质及其构效关系的研究
引用本文:庄惠生,王琼娥,陈国南,黄金陵.6种不同取代基的双吖啶类探针的化学发光性质及其构效关系的研究[J].光谱学与光谱分析,2004,24(12):1514-1517.
作者姓名:庄惠生  王琼娥  陈国南  黄金陵
作者单位:1. 东华大学环境科学与工程学院,上海,200051
2. 东华大学化学化工学院,上海,200051
3. 福州大学化学化工学院,福建,福州,350002
基金项目:国家自然科学基金项目 (2 0 2 770 0 5),福建省自然科学基金项目 (C0 1 1 0 0 0 5),东华大学科技发展基金项目等资助
摘    要:研究了10,10’-二甲基-9,9’-双吖啶二硝酸盐(DMBAI)N);10,10’-二甲基-3,3’-二磺酸基-9,9’-双吖啶(I)MDSBA);3,3’-二磺酸基-9,9’-双吖啶二硝酸盐(DSBADN);10,10’-二乙羧基-9,9’-双吖啶硝酸盐(DEBADN);10,10’一二甲基-3,3’-二氨基-9,9’-双吖啶(DMDABA)和10,10’-二(4-氨基丁基)-9,9’-双吖啶硝酸盐(DABADN)等6种9,9’-双吖啶类探针的化学发光性质,获得了9,9’-双吖啶类探针的结构与化学发光性质之间的某些关系,为设计合成新型用于化学发光免疫分析的高发光效率的9,9’-双吖啶类探针提供了一定的理论和实验依据。

关 键 词:化学发光免疫分析  二甲基  设计合成  取代基  性质  探针  氨基  构效关系  硝酸盐  实验
文章编号:1000-0593(2004)12-1514-04
修稿时间:2003年3月26日

Study on the Relationships between Chemiluminescent Properties and Molecular Structures of Some Biacridine Probes
ZHUANG Hui-sheng ,WANG Qiong-e ,CHEN Guo-nan ,HUANG Jin-ling . College of Environment Science and Engineering,Donghua University,Shanghai ,China . College of Chemistry and Chemical Engineering,Donghua University,Shanghai ,China . College of Chemistry and Chemical Engineering,Fuzhou University,Fuzhou ,China.Study on the Relationships between Chemiluminescent Properties and Molecular Structures of Some Biacridine Probes[J].Spectroscopy and Spectral Analysis,2004,24(12):1514-1517.
Authors:ZHUANG Hui-sheng  WANG Qiong-e  CHEN Guo-nan  HUANG Jin-ling College of Environment Science and Engineering  Donghua University  Shanghai  China College of Chemistry and Chemical Engineering  Donghua University  Shanghai  China College of Chemistry and Chemical Engineering  Fuzhou University  Fuzhou  China
Institution:College of Environment Science and Engineering, Donghua University, Shanghai 200051, China.
Abstract:The chemiluminescent(CL) properties of biacridine probes, such as 10,10'-dimethyl-3,3'-disulfo-9,9'-biacridine(DMDSBA), 3,3'-disulfo-9,9'-biacridine dinitrate(DSBADN), 10,10'-diethcarboxyl-9,9'-biacridine dinitrate(DEBADN), 10,10'-dimethyl-3,3'-diamino-9,9'-biacridine (DMDABA), and 10,10'-di(4-aminobutyl)-9,9-biacridine dinitrate(DABADN), were studied in this paper, and the relationships between properties and molecular structures were obtained. A new theory and some valuable experimental data have been provided for the investigation and exploitation of the new CL probes for biomacromolecules.
Keywords:Biacridine  Probes  Chemiluminescence  Immunoassay
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