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基于SPR光谱分析的液体折射率测量研究
引用本文:曾捷,梁大开,曾振武,杜燕.基于SPR光谱分析的液体折射率测量研究[J].光谱学与光谱分析,2006,26(4):723-727.
作者姓名:曾捷  梁大开  曾振武  杜燕
作者单位:南京航空航天大学智能材料与结构航空科技重点实验室,江苏,南京,210016
基金项目:国家自然科学基金 , 航空基金 , 国家自然科学基金
摘    要:文章从电磁场理论和射线理论的角度, 详细讨论了光纤表面等离子体波传感器工作原理, 分析了表面等离子体共振(SPR)光谱共振波长与液体介质折射率之间的对应关系. 采用相关光谱检测技术, 获得八种不同类型分析醇所对应的SPR光谱曲线族, 其共振波长随液体折射率的增大而逐渐向长波长方向偏移. 通过对乙醇与乙二醇混合液体所对应的共振光谱分析, 实现对两者配比浓度的测定. 整个传感系统结构简单, 测量光路部分实现全光纤化, 不仅能够对目标测量介质的实时、快速、精确测量, 还可用于特殊测量场合, 实现远程遥测功能.

关 键 词:SPR光谱分析  表面等离子体波  光纤传感器  折射率
文章编号:1000-0593(2006)04-0723-05
收稿时间:2004-12-13
修稿时间:2005-05-28

Study on Measurement of Liquid Refractive Index by Analyzing SPR Spectrum Character
ZENG Jie,LIANG Da-kai,ZENG Zhen-wu,DU Yan.Study on Measurement of Liquid Refractive Index by Analyzing SPR Spectrum Character[J].Spectroscopy and Spectral Analysis,2006,26(4):723-727.
Authors:ZENG Jie  LIANG Da-kai  ZENG Zhen-wu  DU Yan
Institution:The Aeronautical Science Key Laboratory for Smart Material and Structures, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, China
Abstract:The principle of optic fiber surface plasmon resonance sensor is discussed in detail based on the electromagnetic theory and radial theory in the present paper. The relationship between SPR spectrum resonance wavelength and liquid refractive index is also analyzed. Through relative spectrum measurement technology, SPR spectrum curves, whose resonance wavelength increases with increasing liquid refractive index, were obtained for eight different kinds of chemical liquids. The measurement of concentration of mixed solution including ethanol and glycol was performed by analyzing the spectrum attribute. The experimenrtal results show that the sensing system features simple structure and all light transmitted by fiber. It not only realizes rapid, accurate and real time measurement for target medium, but also can be used in some special situations and easily realize long distance measurement.
Keywords:SPR spectrum analysis  Surface plasmon wave  Optic fiber sensor  Refractive index
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