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二氧化碲(TeO2)晶体的Raman光谱研究
引用本文:刘晓静,仇怀利,王爱华,殷绍唐,尤静林,蒋国昌.二氧化碲(TeO2)晶体的Raman光谱研究[J].光谱学与光谱分析,2003,23(3):484-486.
作者姓名:刘晓静  仇怀利  王爱华  殷绍唐  尤静林  蒋国昌
作者单位:1. 中国科学院安徽光学精密机械研究所,安徽,合肥,230031
2. 上海市上海大学钢铁冶金新技术开发应用重点实验室,上海,200072
基金项目:国家自然科学基金资助项目 :No 59832 0 82
摘    要:利用激光显微高温Raman光谱仪 ,测定了TeO2 晶体的常温Raman光谱及高温熔体法生长TeO2 晶体固 液边界层的高温Raman光谱。通过分析 ,指认了TeO2 晶体的常温Raman谱图 2 0 0~ 80 0cm- 1 谱峰的振动模式 ,解析了高温Raman谱图各谱峰的展宽、频移 ,提出了熔体可能的结构基团 ,从而为研究功能性晶体材料生长机理提供了一定依据。

关 键 词:激光显微高温Raman光谱  生长固/液边界层  实时测量  二氧化碲(TeO2)晶体
文章编号:1000-0593(2003)03-0484-03
修稿时间:2002年1月28日

Raman Spectra Study of Tellurium Dioxide (TeO2) Crystal
LIU Xiao-jing,QIU Huai-li,WANG Ai-hua,YIN Shao-tang,YOU Jing-lin and JIANG Guo-chang .Anhui Institute of Optics and Fine Mechanics,Academia Sinica,Hefei ,China.Raman Spectra Study of Tellurium Dioxide (TeO2) Crystal[J].Spectroscopy and Spectral Analysis,2003,23(3):484-486.
Authors:LIU Xiao-jing  QIU Huai-li  WANG Ai-hua  YIN Shao-tang  YOU Jing-lin and JIANG Guo-chang Anhui Institute of Optics and Fine Mechanics  Academia Sinica  Hefei  China
Institution:Anhui Institute of Optics and Fine Mechanics, Academia Sinica, Hefei 230031, China.
Abstract:The room temperature and high temperature Raman spectra of solid/melt growth boundary layers of TeO 2 grown from melt were measured by high-temperature laser-micro-Raman spectrum. By analyzing,vibrational modes of the room temperature Raman spectra peaks of TeO 2 crystal from band 200-800 cm -1 were confimed,the expansion and frequency shift of each peak of the high temperature Raman spectra were interpreted and the possible structure group of the melt was proposed.So,certain foundation for studying the growth theory of functional crystal materials was provided.
Keywords:Laser micro-Raman spectrum  Real time meassurement  Solid/melt growth boundary layers  Tellurium dioxide(TeO  2)
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