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Chatham合成钻石紫外阴极发光谱
引用本文:杨勇,亓利剑,袁心强.Chatham合成钻石紫外阴极发光谱[J].光谱学与光谱分析,2003,23(5):913-916.
作者姓名:杨勇  亓利剑  袁心强
作者单位:1. 中国地质大学,武汉,数理系,湖北,武汉,430074
2. 中国地质大学,武汉,宝石学院,湖北,武汉,430074
基金项目:国家自然科学基金资助项目(49503046,49772096)
摘    要:用自制的阴极发光分析仪在JCXA-733电子探针上分析两批美国Chatham公司合成钻石的微区紫外-可见阴极荧光,结果表明Chatham合成钻石具有峰波长为234,268 nm等的紫外阴极荧光谱。不同批次的Chatham钻石的紫外阴极荧光谱特征也有所不同。这些紫外阴极发光谱在天然钻石和人工处理后的天然钻石中都没有发现,可能是Chatham合成钻石的特征谱,因而可能具有一定鉴定价值。经进一步完善后,紫外阴极荧光谱技术有望成为鉴别天然和合成钻石、不同公司合成钻石或同一公司不同批次合成钻石的有效方法。

关 键 词:阴极发光(CL)  合成钻石  金刚石  紫外光谱
文章编号:1000-0593(2003)05-0913-04
修稿时间:2003年1月5日

Ultraviolet Cathodoluminescence Spectra of Chatham Synthetic Diamond
YANG Yong,QI Li-jian,YUAN Xin-qiang.Ultraviolet Cathodoluminescence Spectra of Chatham Synthetic Diamond[J].Spectroscopy and Spectral Analysis,2003,23(5):913-916.
Authors:YANG Yong  QI Li-jian  YUAN Xin-qiang
Institution:YANG Yong,QI Li-jian,YUAN Xin-qiang 1.Department of Mathematics and Physics,China University of Geosciences,Wuhan 430074,China 2.Gemmological Institute,China University of Geosciences,Wuhan 430074,China
Abstract:The ultraviolet cathodoluminescence spectra of two crops of Chatham synthetic diamonds were analyzed by cathodoluminescence spectrometer made by ourselves and mounted on JCXA-733 EPMA. The research results show that the cathodoluminescence spectra of Chatham synthetic diamonds have ultraviolet peaks at 234 and 268 nm. They are also different shapes of peaks for the two crops of synthetic diamonds. We did not find the same ultraviolet cathodoluminescence peaks with natural diamonds, and believe that they may be characteristic peaks and valuable fingerprints of Chatham synthetic diamonds. After being perfected, the technology of ultraviolet cathodoluminescence spectra might become an effective method for differentiating synthetic diamonds and natural diamonds, or synthetic diamonds from different company, or even synthetic diamonds from the same company but from different crops.
Keywords:Cathodoluminescence(CL)  Synthetic diamond  Diamond  Ultraviolet(UV) spectrum
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