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连苯三酚氧化产物及其金属配合物的合成及表征
引用本文:杨融生,蔡金万,孙燕琼,张汉辉.连苯三酚氧化产物及其金属配合物的合成及表征[J].光谱学与光谱分析,2000,20(5):645-647.
作者姓名:杨融生  蔡金万  孙燕琼  张汉辉
作者单位:福州大学化学系,350002,福州
基金项目:结构化学国家重点实验室资助,福建省自然科学基金资助
摘    要:在ab initio量子化学研究的基础上,研究了连苯三酚的氧化反应,并合成了连苯三酚氧化产物与水合肼的缩合物及其金属配合物,用IR、Raman光谱和热重分析,确定了配合物的组成及THBO的可能结构。

关 键 词:连苯三酚  水合肼  金属配合物  氧化  酚醌  表征

Synthesis and Characterization of the Oxidation Product of the 1,2,3-trihydroxybenzene and Its Metalic Complexes
Rongsheng YANG,Jinwan CAI,Yanqiong SUN,Hanhui ZHANG.Synthesis and Characterization of the Oxidation Product of the 1,2,3-trihydroxybenzene and Its Metalic Complexes[J].Spectroscopy and Spectral Analysis,2000,20(5):645-647.
Authors:Rongsheng YANG  Jinwan CAI  Yanqiong SUN  Hanhui ZHANG
Institution:Department of Chemistry, Fuzhou University, 350002 Fuzhou.
Abstract:The oxidation reaction mechanism of the 1,2,3 -t rihydroxybenzene was studied by the Ab initio calculation of the quantum chemist ry. The derivative of the hydrazine and THBO(the reaction product of the 1,2,3- trihydroxybenzene and H 2O 2) and its metal complexes were synthesized and cha racterized by the IR,Raman spectrum and thermogravimetric analysis. The composit ion of these complexes and the possible structure of THBO were confirmed.
Keywords:trihydroxybenzene    Hydrazine    Metal co mplexes    Vibration spectrum    
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