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傅里叶变换红外光谱和近红外傅里叶变换拉曼光谱法无损鉴定中国字画
引用本文:那娜,欧阳启名,乔玉青,欧阳津,王雅辉.傅里叶变换红外光谱和近红外傅里叶变换拉曼光谱法无损鉴定中国字画[J].光谱学与光谱分析,2004,24(11):1327-1330.
作者姓名:那娜  欧阳启名  乔玉青  欧阳津  王雅辉
作者单位:北京师范大学化学系,北京,100875;首都师范大学艺术系,北京,100037
基金项目:全国艺术科学“十五”规划国家资助课题(01BF40)资助
摘    要:利用傅里叶变换红外(FTIR)和近红外傅里叶变换拉曼(NIRFT-Raman)光谱法鉴定了中国字画,结果表明:与荧光光谱法相比,根据谱峰的强度和位置可更容易地将真伪字画区别开来。拉曼光谱和红外光谱相互印证,互相补充,在鉴定中具有快速、准确、操作简单、重复性好、不需对样品进行预处理的优点,适于珍贵字画的无损鉴定。

关 键 词:傅里叶变换红外光谱法  近红外傅里叶变换拉曼光谱法  无损鉴定  中国字画
文章编号:1000-0593(2004)11-1327-04
修稿时间:2003年6月28日

Rapid and Non-Destructive Identification of Calligraphies by Fourier Transform Infrared Spectroscopy and Fourier Transform Raman Spectroscopy
NA Na ,OUYANG Qi ming ,QIAO Yu qing ,OUYANG Jin ,WANG Ya hui.Rapid and Non-Destructive Identification of Calligraphies by Fourier Transform Infrared Spectroscopy and Fourier Transform Raman Spectroscopy[J].Spectroscopy and Spectral Analysis,2004,24(11):1327-1330.
Authors:NA Na  OUYANG Qi ming  QIAO Yu qing  OUYANG Jin  WANG Ya hui
Institution:Department of Chemistry, Beijing Normal University, Beijing 100875, China.
Abstract:A rapid and non destructive method was used to discriminate between calligraphies by means of Fourier transform infrared (FTIR) and FT Raman spectroscopy in this paper. In order to discriminate two real calligraphies of Ouyang Zhong shi from two counterfeit ones, the authors investigated the inkpad and the rice paper of the calligraphies by means of FT Raman spectroscopy and tested the inkpad and the ink mark of the calligraphies by means of FTIR spectroscopy. It could be seen that the tiny, delicated varied chemical components of the real and the counterfeit calligraphies lead to different characters in vibration frequencies of IR and Raman functional groups and also the real calligraphies have the perfect reiteration. So the authors can discriminate between the real and the counterfeit calligraphies. It is proved that FTIR and FT Raman are useful in the non destructive identification of calligraphies and more precise and quicker than traditional approaches.
Keywords:Fourier transform infrared spectroscopy  Fourier transform Raman spectroscopy  Non-destructive identification  Calligraphies
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