| 碱性溶液中纳米钯膜电极表面CO、CN-吸附的红外反射光谱研究 |
| |
| 引用本文： | 孙世刚,蔡丽蓉,周志有,陈声培.碱性溶液中纳米钯膜电极表面CO、CN-吸附的红外反射光谱研究[J].光谱学与光谱分析,2000,20(5):601-602. |
| |
| 作者姓名： | 孙世刚 蔡丽蓉 周志有 陈声培 |
| |
| 作者单位： | 厦门大学固体表面物理化学国家重点实验室,化学系,物化所,厦门,361005 |
| |
| 基金项目： | 中国科学院资助项目，高等学校博士学科点专项科研项目，29833060，1999038403，， |
| |
| 摘 要： | 以原位ＦＴＩＲ反射光谱研究碱性介质中ＣＯ和ＣＮ＾－在纳米Ｐｄ膜电极上的吸附和共吸附，进一步揭示了纳米薄膜材料的异常红外效应和ＣＯ与ＣＮ＾－共吸附时的相互作用规律。
|
| 关 键 词： | 原位FTIRS CO CN^－ 纳米钯膜电极 吸附 |
In Situ FTIR Spectrocopic Studies of CO and CN- Adsorbed on Electrode of Nanometer Thin Film of Palladium in Alkaline Solutions |
| |
| Shigang SUN,Lirong CAI,Zhiyou ZHOU,Shengpei CHEN.In Situ FTIR Spectrocopic Studies of CO and CN- Adsorbed on Electrode of Nanometer Thin Film of Palladium in Alkaline Solutions[J].Spectroscopy and Spectral Analysis,2000,20(5):601-602. |
| |
| Authors: | Shigang SUN Lirong CAI Zhiyou ZHOU Shengpei CHEN |
| |
| Institution: | State Key Laboratory for Physical Chemistry of Solid Surfaces, Department of Chemistry, Institute of Physical Chemistry, Xiamen University, 361005 Xiamen. |
| |
| Abstract: | The adsorption and coadsorption of CO and CN- - on electrode of nanometer thin film of palladium (nm-Pd/GC)was studied by usin g in situ FTIR spectroscopy.The results demonstrated that the nm-Pd/GC electrod e exhibited abnormal infrared effects (AIREs) in alkaline solutions as in acid s olutions.The characters of AIREs,i.e.,the inversion of the direc tion of IR band,the augmentation of FWHM and the significant enhancement of IR a bsorption by adsorbed species were observed in all cases of adsorption and coads orption of CO and CN--.It has been illustrated that strong interaction is exis ted between adsorbed CO and CN-- on nm-Pd/GC surface.The study has contribute d towards understanding the surface processes of chemisorption as well as to rev eal the origin of nanometer size-effects of thin film materials. |
| |
| Keywords: | nm-Pd/GC CO CN-- In situ FTIRS AIRE S |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
