| 杂多阴离子柱撑水滑石层柱相互作用的光电子能谱研究 |
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| 引用本文： | 李兴林.杂多阴离子柱撑水滑石层柱相互作用的光电子能谱研究[J].光谱学与光谱分析,1998,18(2):149-151. |
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| 作者姓名： | 李兴林 |
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| 作者单位： | 中国科学院长春应用化学研究所 |
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| 摘 要： | 本文用Ｘ－光电子能谱仪对二十二种同多和杂多阴离子柱撑水滑石层和柱中元素电子结合能的化学位移进行了研究。同时通过ＩＲ，ＸＲＤ的分析，对ＸＰＳ结果的讨论提供了一定的补充，探讨了同层不同柱，同性不同层的ＰＯＭ－ＬＤＨＳ的层柱相互作用机理。
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| 关 键 词： | XPS 结合能 柱撑水滑石 杂多阴离子 柱层材料 |
XPS STUDY ON THE INTERACTION OF LAYERS AND PILLARS OF LAYERED DOUBLE HYDROXIDES PILLARED WITH HETEROPOLYANION |
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| X Li.XPS STUDY ON THE INTERACTION OF LAYERS AND PILLARS OF LAYERED DOUBLE HYDROXIDES PILLARED WITH HETEROPOLYANION[J].Spectroscopy and Spectral Analysis,1998,18(2):149-151. |
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| Authors: | X Li |
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| Institution: | Changchun Institute of Applied Chemistry, Academia Sinica, Changchun. |
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| Abstract: | Layered double hydroxides (LDHs) pillared with heteropolyanions were studied using XPS spectra.The shift of the binding energy of Mg 2P ,Al 2P ,Zn 2P 3/2 ,Cu 2P 3/2 ,Co 2P 3/2 ,N 1s ,Si 2P ,W 4f 7/2 and Mn 2P 3/2 as well as the mechanism of the interaction of layers and pillars were discussed. |
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| Keywords: | XPS Binding energy Pillared LDHs Heteropolyanion |
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