| 金属钌(Ⅱ)三螯形化合物的吸收光谱和发射光谱 |
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| 引用本文： | 吕卫星,施建军,王怀兵.金属钌(Ⅱ)三螯形化合物的吸收光谱和发射光谱[J].光谱学与光谱分析,1999,19(5):677-679. |
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| 作者姓名： | 吕卫星 施建军 王怀兵 |
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| 作者单位： | 1. 中国科学技术大学高分子科学与工程系,230026,合肥;合肥联合大学物理教研室,230022,合肥
2. 合肥联合大学化工系,230022,合肥 |
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| 基金项目： | 安徽省高校自然科学基金 |
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| 摘 要： | 通过对１，１０－菲珞琳及４，７－二苯基－１，１０－菲珞琳与钉三螯形化合物的吸收和发射谱分析，研究了钌离子４ｄ态在Ｄ３场作用下的分裂，发现配体的不同光谱会出现红移及吸光强度的变化，并定性地分析了配体影响光谱的影响。
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| 关 键 词： | 金属钌螯合物 紫外可见吸收光谱 发射光谱 |
Photoluminescence and UV-VIS Absorption Spectra Characteristics of Complexes of Ruthenium(Ⅱ) with 1,10-Phenanthroline and 4,7-Diphnyl-1,10-Phenanthroline |
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| Weixing L,Jianjun SHI,Huaibing WANG.Photoluminescence and UV-VIS Absorption Spectra Characteristics of Complexes of Ruthenium(Ⅱ) with 1,10-Phenanthroline and 4,7-Diphnyl-1,10-Phenanthroline[J].Spectroscopy and Spectral Analysis,1999,19(5):677-679. |
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| Authors: | Weixing L Jianjun SHI Huaibing WANG |
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| Institution: | Departement of Polymer Science and Engineering, USTC, 230026 Hefei. |
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| Abstract: | The preparation and spectroscopic characteristics of the tris (1,10-phenanthroline) and tris (4,7-diphenyl-1,10-phenalthroline) complex ions of rathenium (II) are reported. Under the coordinate field with the property of D3 group, the splitting of the 4d state of Ru2+ is discussed. The transitions which give rise to the UV-VIS absorption spectra and emission spectra of the complexes are assigned. The influence of the coordinate substance on the absorptivity and red-shift is discussed as well. |
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