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新型八取代酞菁谱学性质研究
作者姓名:Xia DC  Li WC  Wang HF  Zheng XX  Guo YJ  Yang XQ
作者单位:1. 运城学院化学系,山西运城044000;东北师范大学化学学院,吉林长春130021;山西大学化学与化工学院,山西太原041000
2. 吉林大学集成光电子国家重点实验室,电子科学与工程学院,吉林长春130012
3. 运城学院化学系,山西运城044000;山西大学化学与化工学院,山西太原041000
4. 运城学院化学系,山西运城,044000
基金项目:国家自然科学基金,山西省青年基金,山西省高校基金,运城学院院级重点项目,东北师范大学校内博士后基金
摘    要:对1,4,8,11,15,18,22,25-八氧代正丁基酞菁铜、1,4,8,11,15,18,22,25-八氧代丁酸甲酯基酞菁锰、1,4,8,11,15,18,22,25-八氧代正丁酸甲酯基酞菁铜、1,4,8,11,15,18,22,25-八氧代正丁酸甲酯基酞菁锌这四种新型八取代酞菁的红外光谱、紫外光谱和荧光光谱的性质...

关 键 词:酞菁  新型  八取代  性质

Study on spectra properties of novel octa-substituted phthalocyanines
Xia DC,Li WC,Wang HF,Zheng XX,Guo YJ,Yang XQ.Study on spectra properties of novel octa-substituted phthalocyanines[J].Spectroscopy and Spectral Analysis,2011,31(8):2171-2175.
Authors:Xia Dao-Cheng  Li Wan-Cheng  Wang Hong-Fu  Zheng Xin-Xing  Guo Yan-Jie  Yang Xu-Qing
Institution:College of Chemistry, Yuncheng University, Yuncheng 044000, China. xiadaocheng@yahoo.com.cn
Abstract:The spectrum properties of four novel 1, 4, 8, 11, 15, 18, 22, 25-octaoxybutyl copper phthalocyanine; 1,4,8,11,15,18, 22, 25-octamethoxybutanoate manganese phthalocyanine; 1, 4, 8, 11, 15, 18, 22, 25-octamethoxybutanoate copper phthalocyanine; 1, 4, 8, 11, 15, 18, 22, 25-octamethoxybutanoate zinc phthalocyanine were investigated by infrared, fluorescence and UV-visible spectrum in the the paper. There is no rule in the infrared spectrum of these octa-substituted phthalocyanines. The orders of the Q band, B band and Pc dimer band are different among the above Octa-substituted Phthalocyanines in the UV and fluorescence spectra. The reason is related to the interaction between the ligand and the central metal of these octa-substituted phthalocyanines.
Keywords:
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