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几种不同产地高岭土的漫反射傅里叶红外光谱分析
作者姓名:Li XH  Jiang XP  Chen C  Tu N
作者单位:江西省先进陶瓷材料重点实验室,景德镇陶瓷学院,江西景德镇,333001
基金项目:国家自然科学基金项目(50862005,51062005,91022027); 江西省自然科学基金项目(2008GZC0009,2007GZC1258,2009JX02060); 江西省对外科技合作项目(赣财教[2008]212); 江西省高等学校“先进陶瓷材料”科技创新团队资助
摘    要:分别采用压片法与漫反射法测得几种不同产地高岭土的红外吸收谱图,解析了各高岭土的结构特征与吸收峰值的关系,发现利用漫反射傅里叶红外光谱技术,经K-M函数校正的红外谱图较压片法灵敏度高,也更准确,解析更简单;依据对高频区3700~3600cm-1波数段高岭石OH基特征吸收峰的吸收情况,可快速判断高岭石结晶度,结果与X射线衍射技术所测Hinckley指数(Hi)一致。

关 键 词:漫反射红外  高岭石  结晶度  

Research on diffuse reflectance infrared Fourier transform spectroscopy of kinds of kaolin in various areas
Li XH,Jiang XP,Chen C,Tu N.Research on diffuse reflectance infrared Fourier transform spectroscopy of kinds of kaolin in various areas[J].Spectroscopy and Spectral Analysis,2011,31(1):114-118.
Authors:Li Xiao-Hong  Jiang Xiang-Ping  Chen Chao  Tu Na
Institution:LI Xiao-hong,JIANG Xiang-ping*,CHEN Chao,TU Na Jingdezhen Ceramics Institute,Jingdezhen 333001,China
Abstract:Respectively using pressed method and diffuse reflectance method,the infrared absorption spectrua of sorts of kaolin in various areas were obtained.The relationship between the structure characteristics of kaolin and its absorption peaks was analyzed.The results showed that compared with pressed method,the use of diffuse reflectance Fourier transform infrared spectroscopy,combined with the K-M function,results in corrected infrared spectra with high sensitivity and is more accurate and easier to analyze.Fur...
Keywords:Diffuse reflectance infrared Fourier  Kaolinite  Crystallinity  
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