| 含ME4(M＝Mo,W;E＝S,Se)单元簇合物的合成和红外谱表征 |
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| 引用本文： | 洪茂椿,张千峰,曹荣,包木太.含ME4(M＝Mo,W;E＝S,Se)单元簇合物的合成和红外谱表征[J].光谱学与光谱分析,2000,20(6):812-813. |
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| 作者姓名： | 洪茂椿 张千峰 曹荣 包木太 |
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| 作者单位： | 中国科学院福建物质结构研究所,结构化学国家重点实验室,福州,350002 |
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| 基金项目： | 中国科学院资助项目，中国科学基金，，，， |
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| 摘 要： | 合成了一系列单立方烷Ｍ－Ｆｅ－Ｓｅ和Ｍ－Ｃｕ（Ａｇ）－Ｓ（Ｓｅ）簇合物，并用ＵＶ，ＩＲ和Ｘ－光衍射等方法对上述簇合物进行了分析。
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| 关 键 词： | 族合物 合成 结构 单立方烷 红外光谱 |
Syntheses,Reactions and Spectroscopic Properties of Cluster Compounds Containing ME4(M=Mo,W;E=S,Se) Units |
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| Maochun HONG,Qianfeng ZHANG,Rong CAO,Mutai BAO.Syntheses,Reactions and Spectroscopic Properties of Cluster Compounds Containing ME4(M=Mo,W;E=S,Se) Units[J].Spectroscopy and Spectral Analysis,2000,20(6):812-813. |
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| Authors: | Maochun HONG Qianfeng ZHANG Rong CAO Mutai BAO |
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| Institution: | Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, State Key Laboratory of Structural Chemistry, 350002 Fuzhou. |
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| Abstract: | The synthetic reactions and spectroscopic studied of molybdenum (tungsten) -copper (silver, iron) -sulphur (selenium) cluster compounds, which can be prepared by the stepwise or unit construction reactions through the successive addition ML (L = Cl, Br, Sr, R2 etc) across six edges or four faces of ME4 (M = Mo, W; E = S, Se) tetrahedra, are described. A series of Mo (W)-Cu-S cluster compounds, (Et4N)2 MCu2E4 (S2CNR2)2], (Et4N)2 MCu2E3O (S2CNR2)2], MCu2E4 (dppe)2] (dppe = bis (diphenylphosphine) ethane), (Et4N)2 MCu3E4 (S2CNR2)4] (M = Mo, E = Se, R = Et (1a), R2 = C4H8 (1b), R = PhCH2 (lc)), (Et4N)2 MCu4E4 (S2CNR2)4] (M = Mo, E = Se, R = Me (2)) (Et4N)2 M2Cu4S8 (S2CNEt2)2], (Et4N)2 M2Cu4S6O2- (S2CNC4H8)2], Mo2Cu4S8 (dppm)2], Mo2Cu4S6O2 (dppm)2], (dppm = bis (diphenylphosphine) -methane), (Et4N)4 (ME4Cu10L12) (M = Mo, E = Se, L = PhCH2S (3)), MoFe3Se4 (mu-R2NCS2)2 (R2NCS2)4 have been prepared and characterized by UV, IR and X-ray diffraction analyses. |
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| Keywords: | Syntheses Reaction Cluster compounds Structure |
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