| R6G单分子表面增强共振拉曼散射光谱探测研究 |
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| 引用本文： | 周增会,刘力,肖繁荣,王桂英,徐至展.R6G单分子表面增强共振拉曼散射光谱探测研究[J].光谱学与光谱分析,2005,25(12):1986-1990. |
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| 作者姓名： | 周增会 刘力 肖繁荣 王桂英 徐至展 |
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| 作者单位： | 中国科学院上海光学精密机械研究所,强场激光物理国家重点实验室,上海,201800;中国科学院研究生院,北京,100039;中国科学院上海光学精密机械研究所,强场激光物理国家重点实验室,上海,201800 |
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| 基金项目： | 国家重点基础研究发展计划基金（“973”计划）（2002CB713808）和上海市光科技重点基金（01DJG018）资助项目 |
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| 摘 要： | 以共焦显微系统为平台,研究了不同浓度的R6G银溶胶的表面增强共振拉曼散射(SERRS)光谱, 结果表明不同浓度溶液中的R6G分子表现出了不同的光谱特性。在浓度为10-13mol·L-1的R6G银溶胶中 得到了R6G单分子的表面增强共振拉曼散射光谱,观察到了一些光谱非均匀变化现象,如谱色散、谱线的 强度起伏、拉曼谱的偏振化以及分子的闪烁等,并对这些现象进行了分析,证明得到的是R6G单分子的 SERRS光谱。文章还对单分子检测中的一些关键问题进行了分析与讨论,确定了单分子SERRS光谱检测的 适当条件。
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| 关 键 词： | 表面增强拉曼散射 表面增强共振拉曼散射 单分子光谱 若丹明6G 光谱偏振 |
| 文章编号： | 1000-0593(2005)12-1986-05 |
| 收稿时间： | 2004-12-28 |
| 修稿时间： | 2005-04-26 |
Probing R6G Single Molecules by Surface-Enhanced Resonance Raman Scattering |
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| ZHOU Zeng-hui,LIU Li,XIAO Fan-rong,WANG Gui-ying,XU Zhi-zhan.Probing R6G Single Molecules by Surface-Enhanced Resonance Raman Scattering[J].Spectroscopy and Spectral Analysis,2005,25(12):1986-1990. |
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| Authors: | ZHOU Zeng-hui LIU Li XIAO Fan-rong WANG Gui-ying XU Zhi-zhan |
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| Institution: | State Key Laboratory of High Field Laser Physics, Shanghai Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Shanghai 201800, China. |
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| Abstract: | R6G was incubated in three kinds of silver colloid with different low concentrations, and its surface-enhanced resonance Raman scattering (SERRS) was studied with a confocal microscopy system. Each sample exhibited different spectrum character. At the single-molecule level the SERRS-spectra were recorded in 10(-13) mol x L(-1) dye colloidal solution. Some spectral inhomogeneous behavior was recorded such as spectral diffusion, intensity fluctuation of vibrational lines and spectral polarization, and even on/off blinking and splitting of some lines within the spectrum of one molecule. Polarization of excitation light and background subtraction of signal have an important influence on the SERRS spectra detection of single-molecule, which was analyzed in the present paper. |
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| Keywords: | SERS SERRS Single-molecule spectroscopy R6G Spectral polarization |
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