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氢氧化铝共沉淀浮选石墨炉原子吸收测水中铬(Ⅲ)与铬(Ⅵ)
引用本文:李琳.氢氧化铝共沉淀浮选石墨炉原子吸收测水中铬(Ⅲ)与铬(Ⅵ)[J].光谱学与光谱分析,1998,18(3):354-358.
作者姓名:李琳
作者单位:四川联合大学化学系
摘    要:本文了研究了氢氧化铝共沉淀浮选,石墨炉原子吸收光谱法测定天然地表水和饮用水中痕量Cr(Ⅲ)的方法。

关 键 词:  氢氧化铝  分析  共沉淀  浮选  环境水样  水样

GFAAS determination of trace Cr(III) and Cr(VI) after its separation by coprecipitation-floatation with aluminium hydroxide]
L Li,Y Feng,G Huang.GFAAS determination of trace Cr(III) and Cr(VI) after its separation by coprecipitation-floatation with aluminium hydroxide][J].Spectroscopy and Spectral Analysis,1998,18(3):354-358.
Authors:L Li  Y Feng  G Huang
Institution:Department of Chemistry, Sichuan Union University, 610064 Chengdu.
Abstract:A method for determination of trace Cr(III) in natural water and drinking water by GFAAS after separation by coprecipitation-floatation with Al(OH)3 has been studied. Cr(VI) was determined also after being reduced by FeSO4. Conditions of Cr(III) floatation such as pH, the amount of floatation agent and coprecipitator-Aluminium added, the flow rate of nitrogen gas, the floatation time etc. were discussed. The influence of coexisting elements was investigated. The detection limit is 0.027 microg/L (n = 15). For Cr(III) concentration level of 0.5 microg/L, the RSD is 3.4% and the recovery of Cr(III) is 96.0-104.0%.
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