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核磁共振测量乙醇汽油低含水量的实验探索
引用本文:白怀勇,周格,王殿生.核磁共振测量乙醇汽油低含水量的实验探索[J].大学物理实验,2013,26(1):7-11.
作者姓名:白怀勇  周格  王殿生
作者单位:中国石油大学(华东),山东青岛,266580
基金项目:国家级大学生创新训练计划项目(201210425061)
摘    要:为了探索利用核磁共振技术测量乙醇汽油低含水量的方法,测量了不同含水量乙醇汽油的核磁共振横向弛豫时间,发现横向弛豫时间不随含水量的变化而呈现一定规律性的变化,因而尝试加入NH4NO3、NaOH、CuSO4和MnCl2.4H2O来扩大含水量对核磁共振横向弛豫时间的影响。实验结果表明:加入MnCl2.4H2O可使横向弛豫时间随含水量的增加而增加,并拟合出了相应的经验公式。在此基础上提出了乙醇汽油低含水量的核磁共振测量方法,通过测量实例验证了这一方法的有效性和可靠性。

关 键 词:乙醇汽油  含水量  核磁共振  横向弛豫时间

An Experimental Exploration on the NMR Method for Measuring Low Water Content of Ethanol-gasoline
BAI Huai-yong , ZHOU Ge , WANG Dian-sheng.An Experimental Exploration on the NMR Method for Measuring Low Water Content of Ethanol-gasoline[J].Physical Experiment of College,2013,26(1):7-11.
Authors:BAI Huai-yong  ZHOU Ge  WANG Dian-sheng
Institution:(China University of Petroleum,Shandong Qingdao 266580)
Abstract:The transverse relaxation time of ethanol-gasoline in different water content has been measured in order to investigate the NMR method for measuring ethanol-gasoline water content.The outcome indicates that the transverse relaxation time doesn't show a regular change with the increasing water content.For this reason,NH4NO3,NaOH,CuSO4 and MnCl2·4H2O have been used tentatively to expand the influence of ethanol-gasoline water content on transverse relaxation time.The results show that:If MnCl2·4H2O is added to ethanol-gasoline,a quadratic relationship will exist between the transverse relaxation time and the water content.Thus,an innovative method has been found to measure the water content of ethanol-gasoline and the validity and reliability of this method has been verified by experiment.
Keywords:ethanol-gasoline  water content  NMR  transverse relaxation time
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