The reaction of hexaphenylditin with inorganic acids: New mixed oxidation state compounds of Tin |
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| Authors: | T Birchall J P Johnson V Manivannan |
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| Institution: | (1) Department of Chemistry and Institute for Materials Research, McMaster University, L8S 4M1 Hamilton, Ontario, Canada |
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| Abstract: | The solvolysis of hexphenylditin by a variety of inorganic acids leads to the formation of compounds having the empirical formula SnX3. Tin-119 Mössbauer spectroscopy shows that these compounds should be formulated as Sn(II)Sn(IV)X6: in some of these compounds the non-bonding electron pair of the Sn(II) is stereochemically inactive. |
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