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制备低密度pmp泡沫中的热性能研究
引用本文:王朝阳,毛英,罗炫,范虹.制备低密度pmp泡沫中的热性能研究[J].强激光与粒子束,2001,13(5):595-598.
作者姓名:王朝阳  毛英  罗炫  范虹
作者单位:中国工程物理研究院激光聚变研究中心,
基金项目:国家 8 63惯性约束聚变领域资助课题 (863 -4 16-3 -6.1)
摘    要:在聚-4-甲基-1-戊烯(pmp)低密度泡沫的制备中,利用示差扫描量热分析仪对pmp聚合物在均四甲苯/萘所组成的溶剂/非溶剂二元体系中的凝胶化过程进行在线测量,测定了它的凝胶化范围以及凝胶化温度与冷却速率和pmp在溶剂;非溶剂体系中所占比例的关系。利用热重-示差扫描量热系统对所制备的低密度pmp泡沫的热性能进行了分析,得到了泡沫密度变化对热稳定性等的影响。

关 键 词:热重-示差扫描量热分析  凝胶化低密度pmp泡沫  ICF靶材料  热性能  泡沫制备
文章编号:1001-4322(2001)05-0595-04
收稿时间:2001/2/24
修稿时间:2001年2月24日

Studies on thermodynamical properties in preparation of low-density pmp foams
WANG Chao yang,MAO Ying,LUO Xuan,FAN Hong.Studies on thermodynamical properties in preparation of low-density pmp foams[J].High Power Laser and Particle Beams,2001,13(5):595-598.
Authors:WANG Chao yang  MAO Ying  LUO Xuan  FAN Hong
Abstract:Preparation of low density poly (4 methyl 1 pentene) foam (pmp foam) is described. The thermal analysis method is utilized to measure on line the gelation of pmp polymer in the binary solvent (durene/naphthalene) or nonsolvent system. The range of gelation temperature is preliminarily determined. The influence of mixture system composition and the cooling rate during the process of making foams is discussed. TG DSC is applied to determine the thermal properties of low density pmp foams. And the effect of density change on the thermal stability of foams has been studied. These thermal analysis data play a great role in improving the foam quality.
Keywords:TG  DSC system  gelation  low  density pmp foam  material of ICF targets
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