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Influence of Zr(50)Cu(50) thin film metallic glass as buffer layer on the structural and optoelectrical properties of AZO films
作者姓名:张宝庆  刘高鹏  宗海涛  付丽歌  魏志飞  杨晓炜  曹国华
作者单位:School of Materials Science and Engineering;School of Physics and Electronic Information Engineering
基金项目:Project supported by the National Natural Science Foundation of China(Grant No.51571085);the Key Science and Technology Program of Henan Province,China(Grant No.19212210210);the Foundation of Henan Educational Committee,China(Grant No.13B430019);the Henan Postdoctoral Science Foundation,China。
摘    要:Aluminum-doped ZnO(AZO) thin films with thin film metallic glass of Zr(50)Cu(50) as buffer are prepared on glass substrates by the pulsed laser deposition. The influence of buffer thickness and substrate temperature on structural, optical, and electrical properties of AZO thin film are investigated. Increasing the thickness of buffer layer and substrate temperature can both promote the transformation of AZO from amorphous to crystalline structure, while they show(100)and(002) unique preferential orientations, respectively. After inserting Zr(50)Cu(50) layer between the glass substrate and AZO film, the sheet resistance and visible transmittance decrease, but the infrared transmittance increases. With substrate temperature increasing from 25℃ to 520℃, the sheet resistance of AZO(100 nm)/Zr(50)Cu(50)(4 nm) film first increases and then decreases, and the infrared transmittance is improved. The AZO(100 nm)/Zr(50)Cu(50)(4 nm) film deposited at a substrate temperature of 360℃ exhibits a low sheet resistance of 26.7 ?/, high transmittance of 82.1% in the visible light region, 81.6% in near-infrared region, and low surface roughness of 0.85 nm, which are useful properties for their potential applications in tandem solar cell and infrared technology.

关 键 词:aluminum-doped  ZnO(AZO)  Zr(50)Cu(50)  thin  film  metallic  glass  optoelectrical  properties  morphology

Influence of Zr_(50)Cu_(50) thin film metallic glass as buffer layer on the structural and optoelectrical properties of AZO films
Bao-Qing Zhang,Gao-Peng Liu,Hai-Tao Zong,Li-Ge Fu,Zhi-Fei Wei,Xiao-Wei Yang,Guo-Hua Cao.Influence of Zr(50)Cu(50) thin film metallic glass as buffer layer on the structural and optoelectrical properties of AZO films[J].Chinese Physics B,2020(3):361-368.
Authors:Bao-Qing Zhang  Gao-Peng Liu  Hai-Tao Zong  Li-Ge Fu  Zhi-Fei Wei  Xiao-Wei Yang  Guo-Hua Cao
Institution:(School of Materials Science and Engineering,Henan Polytechnic University,Jiaozuo 454000,China;School of Physics and Electronic Information Engineering,Henan Polytechnic University,Jiaozuo 454000,China)
Abstract:Aluminum-doped ZnO(AZO) thin films with thin film metallic glass of Zr50Cu50 as buffer are prepared on glass substrates by the pulsed laser deposition. The influence of buffer thickness and substrate temperature on structural, optical, and electrical properties of AZO thin film are investigated. Increasing the thickness of buffer layer and substrate temperature can both promote the transformation of AZO from amorphous to crystalline structure, while they show(100)and(002) unique preferential orientations, respectively. After inserting Zr50Cu50 layer between the glass substrate and AZO film, the sheet resistance and visible transmittance decrease, but the infrared transmittance increases. With substrate temperature increasing from 25℃ to 520℃, the sheet resistance of AZO(100 nm)/Zr50Cu50(4 nm) film first increases and then decreases, and the infrared transmittance is improved. The AZO(100 nm)/Zr50Cu50(4 nm) film deposited at a substrate temperature of 360℃ exhibits a low sheet resistance of 26.7 ?/, high transmittance of 82.1% in the visible light region, 81.6% in near-infrared region, and low surface roughness of 0.85 nm, which are useful properties for their potential applications in tandem solar cell and infrared technology.
Keywords:aluminum-doped ZnO(AZO)  Zr50Cu50  thin film metallic glass  optoelectrical properties  morphology
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