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Comparative analysis of energy-level splitting of Pr3+ doped in LiYF4 and LiBiF4 crystals: a complete energy matrix calculation
引用本文:段美玲,邝小渝,张彩霞,柴瑞鹏.Comparative analysis of energy-level splitting of Pr3+ doped in LiYF4 and LiBiF4 crystals: a complete energy matrix calculation[J].中国物理 B,2011,20(1):13102-013102.
作者姓名:段美玲  邝小渝  张彩霞  柴瑞鹏
作者单位:Institute of Atomic and Molecular Physics, Sichuan University, Chengdu 610065, China
基金项目:Project supported by the National Natural Science Foundation of China (Grant Nos. 10774103 and 10974138).
摘    要:

关 键 词:能量矩阵  能级分裂  掺杂晶体  计算  LiYF4晶体  稀土掺杂  镨离子  离子含量
收稿时间:2010-01-19
修稿时间:2/8/2010 12:00:00 AM

Comparative analysis of energy-level splitting of Pr3+ doped in LiYF4 and LiBiF4 crystals: a complete energy matrix calculation
Duan Mei-Ling,Kuang Xiao-Yu,Zhang Cai-Xia and Chai Rui-Peng.Comparative analysis of energy-level splitting of Pr3+ doped in LiYF4 and LiBiF4 crystals: a complete energy matrix calculation[J].Chinese Physics B,2011,20(1):13102-013102.
Authors:Duan Mei-Ling  Kuang Xiao-Yu  Zhang Cai-Xia and Chai Rui-Peng
Institution:Institute of Atomic and Molecular Physics, Sichuan University, Chengdu 610065, China;Institute of Atomic and Molecular Physics, Sichuan University, Chengdu 610065, China;Institute of Atomic and Molecular Physics, Sichuan University, Chengdu 610065, China;Institute of Atomic and Molecular Physics, Sichuan University, Chengdu 610065, China
Abstract:Based on the combination of Racah's group-theoretical consideration with Slater's wavefunction, a 91 × 91 complete energy matrix is established in tetragonal ligand field D2d for Pr3+ ion. Thus, the Stark energy-levels of Pr3+ ions doped separately in LiYF4 and LiBiF4 crystals are calculated, and our calculations imply that the complete energy matrix method can be used as an effective tool to calculate the energy-levels of the systems doped by rare earth ions. Besides, the influence of Pr3+ on energy-level splitting is investigated, and the similarities and the differences between the two doped crystals are demonstrated in detail by comparing their several pairs of curves and crystal field strength quantities. We see that the energy splitting patterns are similar and the crystal field interaction of LiYF4:Pr3+ is stronger than that of LiBiF4:Pr3+.
Keywords:energy levels splitting  rare earth ions  complete energy matrix
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