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Analysis of equation of state and thermodynamic functions for trans-decahydronaphthalene up to 200~MPa and 446~K
Authors:Li Ming  Chen Cui-Ling  Sun Jiu-Xun  Tian Rong-Gang and Xiao Jian-Rong
Institution:[1]Department of Mathematics and Physics, Guilin University of Technology, Guilin 541004, China [2]Department of Mathematics Science, Guangxi Normal University, Gailin 541004, China [3]Department of Applied Physics, University of Electronic Science and Technology, Chengdu 610054, China
Abstract:This paper develops a modified Tait equation of state (EOS) for trans-decahydronaphthalene with four parameters A, B, V0 and P0 being treated as linear functions of temperature. The coefficients contained in these functions are determined through fitting the experimental compression data in the literature between 293~K and 446~K and at pressures from 10 to 200~MPa. Expressions for the thermal expansivity, isothermal compressibility and thermodynamic quantities are deduced and the numerical results are analytically derived. The numerical results show that the precision of the modified Tait EOS developed in this paper is superior to the EOS in the literature.
Keywords:trans-decahydronaphthalene  Tait equation  thermal expansivity  isothermal compressibility
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