首页 | 本学科首页   官方微博 | 高级检索  
     检索      


Impact of composition ratio on the structure and optical properties of (1-x)MnFe2O4/(x)ZnMn2O4 nanocomposite
Authors:Zein K Heiba  Mohamed Bakr Mohamed  Ali A Alkathiri  Sameh I Ahmed  A A Alhazime
Institution:1.Department of Physics, Faculty of Science, Ain shams University, Cairo 11566, Egypt;2.Physics Department, Faculty of Science, Taibah University, Al-Madina al Munawarah, Saudi Arabia;3.Depatment of Physics, College of Science, Taif University, P. O. Box 11099, Taif 21944, Saudi Arabia
Abstract:($1-x$)MnFe$_{2}$O$_{4}$ (MFO)/$x$ZnMn$_{2}$O$_{4}$ (ZMO) ($x=0$, 0.2, 0.5, 0.8, and 1.0) nanocomposite samples were prepared using co-precipitation procedure. The phase percentage, cell parameters, and crystallite size of MFO and ZMO phases in each nanocomposite sample were calculated using Rietveld refinement procedure. The x-ray diffraction (XRD) analysis and Fourier-transform infrared spectroscopy techniques established the variation in the lattice parameters of each phase are due to permutation of all cations among the octahedral and tetrahedral sites of MFO and ZMO. The different oxidation states of different ions in all samples were determined using x-ray photoelectron spectroscopy (XPS) technique. The variation in absorbance of the nanocomposite samples with composition parameter ($x$) is dependent on the wavelength region. The optical bandgap of the nanocomposite samples is decreased as the content of ZMO phase increased. The effect of alloying on the refractive index, extinction coefficient, dielectric constant, optical conductivity, and the nonlinear optical behaviors of all samples were studied in detail. The nanocomposite sample $x=0.5$ disclosed upgraded optical parameters with the highest refractive index, optical conductivity, and PL intensity, which nominate it to be functional in various application fields.
Keywords:MFO and ZMO composite  XPS  structure  optical  
点击此处可从《中国物理 B》浏览原始摘要信息
点击此处可从《中国物理 B》下载免费的PDF全文
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号